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/Subject (Pd-catalysed arylation/acetoxylation cascade, the methodology previously reported by our laboratory, was applied in the functionalisation of unsymmetrical dienes. Both explored classes of compounds, isoquinoline and beta -carboline derived dienes, afforded single regioisomers. Although further improvements of the process are necessary, primarily due to lower yields, described functionalisation of the studied compounds might be useful in the synthesis of emetine and related naturally occurring compounds.)
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Milena Simic
Milos Petkovic
Predrag Jovanovic
Gordana Tasic
Vladimir Savic
Pd-catalysed arylation/acetoxylation cascade, the methodology previously reported by our laboratory, was applied in the functionalisation of unsymmetrical dienes. Both explored classes of compounds, isoquinoline and beta -carboline derived dienes, afforded single regioisomers. Although further improvements of the process are necessary, primarily due to lower yields, described functionalisation of the studied compounds might be useful in the synthesis of emetine and related naturally occurring compounds.
10.2298/JSC170317046S
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Article
Milena Simic
Milos Petkovic
Predrag Jovanovic
Gordana Tasic
Vladimir Savic
Simic2017
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Journal of the Serbian Chemical Society
dec
12
1335--1341
{Synthesis of substituted allyl acetates from heterocyclic dienes by pd-promoted arylation-acetoxylation cascade}
http://www.doiserbia.nb.rs/Article.aspx?ID=0352-51391700046S
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