Measurement and prediction of physical properties of aqueous sodium salt of L-phenylalanine

Sahil Garg, Azmi Mohd Shariff, Muhammad Shuaib Shaikh, Bhajan Lal, Asma Aftab, Nor Faiqa

Abstract


Physical properties such as density, refractive index and viscosity of aqueous sodium salt of l-phenylalanine (Na-Phe) were investigated in this work. These properties were measured over a temperature range of 298.15-
-343.15 K, and at atmospheric pressure. The mass fractions (w) of Na-Phe were 0.05, 0.10, 0.15, 0.20, 0.25, 0.30, 0.35 and 0.40 respectively. The analysis of the experimental data shows that the values of density, refractive index and viscosity decrease with an increase in temperature at any constant concentration of Na-Phe. However, these values increase with the rise of concentration isothermally. The density values were used for estimation of thermal expansion coefficient. The thermal expansion coefficient increases slightly with the increase in temperature and concentration. Density and refractive index data were correlated using modified Graber equation, while, viscosity data were correlated using modified Vogel-Tamman-Fulcher (VTF) equation. In all the cases, a quantitative analysis of the influence of temperature and concentration was carried out.

Keywords


Density; Refractive index; Viscosity; Thermal expansion coef¬ficient; ANOVA

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DOI: http://dx.doi.org/10.2298/JSC160222081G

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