Solubility and degradation of paracetamol in subcritical water

Main Article Content

Zuhal Emire
Erdal Yabalak
http://orcid.org/0000-0002-4009-4174
Özkan Görmez
Ahmet Murat Gizir

Abstract

: In this study, solubility and degradation of paracetamol were exam­ined using subcritical water. The effect of temperature and static time was investigated during the solubility process in subcritical water at constant pres­sure (50 bar). The experimental results showed that temperature and static time have crucial effects on the degradation and solubility rates. The maximal solubility of paracetamol was obtained at 403 K as (14.68±0.74)×103. An approximation model for the solubility of paracetamol was proposed. O2 and H2O2 were used for the degradation of paracetamol. The maximum degradation rate was found as 68.66±1.05 % and 100±0.00 % using O2 and H2O2, res­pectively.

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How to Cite
[1]
Z. Emire, E. Yabalak, Özkan Görmez, and A. M. Gizir, “Solubility and degradation of paracetamol in subcritical water”, J. Serb. Chem. Soc., vol. 82, no. 1, pp. 99–106, Feb. 2017.
Section
Environmental Chemistry
Author Biographies

Zuhal Emire, Mersin University, Faculty of Arts and Science, Department of Chemistry, Çiftlikköy Campus, TR-33343, Mersin

Faculty of Arts and Science, Department of Chemistry

Erdal Yabalak, Mersin University, Faculty of Arts and Science, Department of Chemistry, Çiftlikköy Campus, TR-33343, Mersin

Faculty of Arts and Science, Department of Chemistry

Özkan Görmez, Mersin University, Faculty of Arts and Science, Department of Chemistry, Çiftlikköy Campus, TR-33343, Mersin

Faculty of Arts and Science, Department of Chemistry

Ahmet Murat Gizir, Mersin University, Faculty of Arts and Science, Department of Chemistry, Çiftlikköy Campus, TR-33343, Mersin

Faculty of Arts and Science, Department of Chemistry

References

C. R. Gadipelly, V. K. Rathod, K. V. Marathe, J. Mol. Catal., A: Chem. 414 (2016) 116

C. Gadipelly, A. Pérez-González, G. D. Yadav, I. Ortiz, R. Ibáñez, V. K. Rathod, K. V. Marathe, Ind. Eng. Chem. Res. 53 (2014) 11571

L. Yang, L. E. Yu, M. B. Ray, Water Res. 42 (2008) 3480

M. Magureanu, N. B. Mandache, V. I. Parvulescu, Water Res. 81 (2015) 124

J. Liu, Q. Sun, C. Zhang, H. Li, W. Song, N. Zhang, X. Jia, Desalin. Water Treat. 57 (2016) 11386

K. Ikehata, N. J. Naghashkar, M. G. El-Din, Ozone Sci. Eng. 28 (2006) 353

R. A. Granberg, A. C. Rasmuson, J. Chem. Eng. Data. 44 (1999) 1391

O. Gimeno, J. F. Garcia-Araya, F. J. Beltran, F. J. Rivas, A. Espejo, Chem. Eng. J. 290 (2016) 12

A Mashayekh-Salehi, G. Moussavi, Desalin. Water Treat. 57 (2016) 12861

L. A. Schaider, R. A. Rudel, J. M. Ackerman, S. C. Dunagan, J. G. Brody, Sci. Total Environ. 468 (2014) 384

T. A. Ternes, Water Res. 32 (1998) 3245

D. W. Kolpin, E. T. Furlong, M. T. Meyer, E. M. Thurman, S. D. Zaugg, L. B. Barber, H. T. Buxton, Environ. Sci. Technol. 36 (2002) 1202

D. J. Miller, S. B. Hawthorne, A. M. Gizir, A. A. Clifford, J. Chem. Eng. Data 43 (1998) 1043

J. Mathis, A. M. Gizir, Y. Yang, J. Chem. Eng. Data 49 (2004) 1269

B. Kayan, Y. Yang, E. J. Lindquist, A. M. Gizir, J. Chem. Eng. Data 55 (2010) 2229

B. Kayan, B. Gözmen, J. Hazard. Mater. 201 (2012) 100

G. Zhang, I. Okajima, T. Sako, J. Supercrit. Fluids 112 (2016) 136

J, Levec, A. Pintar, Catal. Today 124 (2007) 172

R. S. Ribeiro, A. M. T. Silva, J. L. Figueiredo, J. L. Faria, H. T. Gomes, Appl. Catal., B 187 (2016) 428

P. R. Gogate, A. B. Pandit, Adv. Environ. Res. 8 (2004) 501

J. Fu, G. Z. Kyzas, Chin. J. Catal. 35 (2014) 1

M. S. Chang, J. Y. Shen, S. H. Yang, G. J. Wu, J. Hazard. Mater. 192 (2011) 1203

E. Yabalak, Ö. Görmez, B. Gözmen, A. M. Gizir, Int. J. Ind. Chem. 6 (2015) 23

M. Khoubnasabjafari, A. Shayanfar, F. Martinez, W. E. Acree Jr., A. Jouyban, J. Mol. Liq. 219 (2016) 435

X. Sheng, Q. Wang, Z. Xiong, C. Chen, Fluid Phase Equilib. 415 (2016) 8

E. Yabalak, A. M. Gizir, J. Serb. Chem. Soc. 78 (2013) 1013

E. Yabalak, PhD Thesis, Mersin University, 2015

B. Kapalavavi, J. Ankney, M. Baucom, Y. Yang, J. Chem. Eng. Data 59 (2014) 912

P. D. Vaidya, V. V. Mahajani, Adv. Environ. Res. 6 (2002) 429

M. Klavariotia, D. Mantzavinos, D. Kassinos, Environ. Int. 35 (2009) 402

B. Gözmen, B. Kayan, A. M. Gizir, A. Hesenov, J. Hazard. Mater. 168 (2009) 129

J. A. Onwudili, P. T. Williams, Fuel 85 (2006) 75

J. Kronholm, J. Kalpala, K. Hartnen, M. L. Riokkola, J. Supercrit. Fluids 23 (2002) 123

J. A. Onwudili, P. T. Williams, J. Supercrit. Fluids 39 (2007) 399

V. M. Daskalaki, E. S. Timotheatou, A. Katsaounis, D. Kalderis, Desalination 274 (2011) 200

A. H. Gemeay, I. A. Mansour, R. G. El-Sharkawy, A. B. Zaki, J. Mol. Catal., A: Chem. 193 (2003) 109

A. Aleboyeh, H. Aleboyeh, Y. Moussa, Environ. Chem. Lett. 1 (2003) 161

M. B. Kasiri, A. R. Khataee, Desalination 270 (2011) 15.