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/Author (Bozinovic, Nina and Solaja, Bogdan and Opsenica, Igor)
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/Title ({Microwave-assisted synthesis of azepines via nucleophilic aromatic substitution})
/Keywords (azepines,heterocycles,microwave irradiation,nucleophilic aromatic substitution,transition-metal-free conditions)
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/Subject (A novel and efficient route has been developed to afford 5 H -dipyridoazepine derivatives from primary amines and 3,3'-\( Z \)-ethene-1,2-diylbis\(4-chloropyridine\). The protocol based on the double nucleophilic aromatic substitution provides a valuable synthetic tool for the synthesis of dipyridoazepines. The reaction proceeds without catalyst, under microwave irradiation condition.)
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azepines
heterocycles
microwave irradiation
nucleophilic aromatic substitution
transition-metal-free conditions
2016
Nina Bozinovic
Bogdan Solaja
Igor Opsenica
A novel and efficient route has been developed to afford 5 H -dipyridoazepine derivatives from primary amines and 3,3'-( Z )-ethene-1,2-diylbis(4-chloropyridine). The protocol based on the double nucleophilic aromatic substitution provides a valuable synthetic tool for the synthesis of dipyridoazepines. The reaction proceeds without catalyst, under microwave irradiation condition.
{Microwave-assisted synthesis of azepines via nucleophilic aromatic substitution}
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Nina Bozinovic
Bogdan Solaja
Igor Opsenica
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azepines,heterocycles,microwave irradiation,nucleophilic aromatic substitution,transition-metal-free conditions
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