Electrochemical properties of carbonized bentonite: Scientific paper

Nataša Jović-Jovičić; Danica   Bajuk-Bogdanović; Tatjana   Novaković; Predrag Banković; Aleksandra   Milutinović-Nikolić; Zorica Mojović

doi:10.2298/JSC220127030J

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Published: Nov 23, 2022

Updated: 23.11.2022

DOI: https://doi.org/10.2298/JSC220127030J

Keywords:

Fe(CN)63-/4- electrosorption chloride ion sulfate ion

Nataša Jović-Jovičić

University of Belgrade - Institute of Chemistry, Technology and Metallurgy, Department of Catalysis and Chemical Engineering, Njegoševa 12, 11000 Belgrade, Republic of Serbia

https://orcid.org/0000-0001-9940-9508

Danica Bajuk-Bogdanović

2Faculty of Physical Chemistry, University of Belgrade, Studentski Trg 12-16, 11000 Belgrade, Republic of Serbia

https://orcid.org/0000-0003-2443-376X

Tatjana Novaković

University of Belgrade - Institute of Chemistry, Technology and Metallurgy, Department of Catalysis and Chemical Engineering, Njegoševa 12, 11000 Belgrade, Republic of Serbia

https://orcid.org/0000-0002-6407-9833

Predrag Banković

University of Belgrade - Institute of Chemistry, Technology and Metallurgy, Department of Catalysis and Chemical Engineering, Njegoševa 12, 11000 Belgrade, Republic of Serbia

https://orcid.org/0000-0002-9732-7370

Aleksandra Milutinović-Nikolić

University of Belgrade - Institute of Chemistry, Technology and Metallurgy, Department of Catalysis and Chemical Engineering, Njegoševa 12, 11000 Belgrade, Republic of Serbia

https://orcid.org/0000-0002-1768-6489

Zorica Mojović

University of Belgrade - Institute of Chemistry, Technology and Metallurgy, Department of Catalysis and Chemical Engineering, Njegoševa 12, 11000 Belgrade, Republic of Serbia

https://orcid.org/0000-0003-4804-0776

Abstract

Organomodified bentonites were obtained by modification of bentonite clay from local mine Bogovina, with four different alkylammonium ions in the amounts that correspond to cation exchange capacity. Carbonized bentonites, obtained by pyrolyzing the organomodified bentonites in the flow of nitrogen, were characterized using XRD, low-temperature N₂ physisorption and Raman spectroscopy. Structural and textural properties of carbonized bentonites depended on the arrangement of alkylammonium cations in the paternal organomodified bentonite, while the Raman spectroscopy confirmed the presence of amorphous carbon. The obtained carbonized bentonites were used for modification of the carbon paste electrode. The modified electrodes were investigated using cyclic voltammetry and electrochemical impedance spectroscopy. The electrosorption of chloride and sulfate anions on carbonized bentonites was studied by chronocoulometry. The results were interpreted in the terms of surface groups and textural properties of the carbonized bentonites.

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[1]

N. Jović-Jovičić, D. . Bajuk-Bogdanović, T. . Novaković, P. Banković, A. . Milutinović-Nikolić, and Z. Mojović, “Electrochemical properties of carbonized bentonite: Scientific paper”, J. Serb. Chem. Soc., vol. 88, no. 1, pp. 41–54, Nov. 2022.

Issue

Vol. 88 No. 1 (2023)

Section

Electrochemistry

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

Zorica Mojović, University of Belgrade - Institute of Chemistry, Technology and Metallurgy, Department of Catalysis and Chemical Engineering, Njegoševa 12, 11000 Belgrade, Republic of Serbia

Funding data

Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja
Grant numbers 451-03-9/2021- -14/200026

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Electrochemical properties of carbonized bentonite Scientific paper