Characterisation of lignite lithotypes from the "Kovin" deposit (Serbia) – Implications from petrographic, biomarker and isotopic analysis

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Danica Mitrović
Nataša Đoković
Dragana Životić
Achim Bechtel
Olga Cvetković
Ksenija Stojanović


Four lignite lithotypes (matrix coal, xylite-rich coal, mixture of matr­ix and mineral-rich coal and mixture of matrix and xylite-rich coal), originating from the Kovin deposit, were investigated in detail. The paper was aimed to determine the main maceral, biomarker and isotopic (δ13C) characteristics of investigated lithotypes. Based on these results the sources and depositional environment of organic matter in 4 lithotypes were established. These samples were also used as substrates for investigation of the influence of diagenetic alt­eration on δ13C signatures of biomarkers, as well as for assessment of the most convenient utilization for each lithotype. The investigated lithotypes differ in accordance with the composition of huminite macerals. Xylite-rich coal not­ably distinguishes from other lithotypes beacuse of the highest content of coni­fer resins vs. epicuticular waxes. The mixture of matrix and mineral-rich coal is characterised by the greatest contribution of algae and fungi and the most intense methanotrophic activity at the time of deposition. In all coal lithotypes diagenetic aromatisation influenced isotopic composition of individual bio­markers. Xylite-rich coal has the poorest grindability properties. However, this coal lithotype is the most suitable for fluidized bed gasification, whereas the mixture of matrix and mineral-rich coal has the lowest applicability for this process. The calorific value decreases in order: xylite-rich coal > matrix coal > mixture of matrix and xylite-rich coal > mixture of matrix and mineral-rich coal. The increase of organic carbon content and calorific value is controlled by the increase of contribution of wood vegetation vs. herbaceous peat-forming plants, as well as by stability of water table during peatification.  


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How to Cite
D. Mitrović, N. Đoković, D. Životić, A. Bechtel, O. Cvetković, and K. Stojanović, “Characterisation of lignite lithotypes from the ‘Kovin’ deposit (Serbia) – Implications from petrographic, biomarker and isotopic analysis”, J. Serb. Chem. Soc., vol. 82, no. 6, pp. 739–754, Aug. 2017.
Author Biographies

Danica Mitrović, University of Belgrade, Innovation Center of the Faculty of Chemistry, Studentski trg 12-16, 11000 Belgrade

Research-assistant, PhD student

Nataša Đoković, University of Belgrade, Innovation Center of the Faculty of Chemistry, Studentski trg 12-16, 11000 Belgrade

Research-assistant, PhD student

Dragana Životić, University of Belgrade, Faculty of Mining and Geology, Đusina 7, 11000 Belgrade

Associate Professor

Achim Bechtel, Montanuniversität Leoben, Department of Applied Geosciences and Geophysics, Peter-Tunner-Str. 5, A-8700 Leoben

Priv.-Doz. Dr. Senior Scientist

Olga Cvetković, University of Belgrade, Center of Chemistry, Institute of Chemistry, Technology and Metallurgy, IChTM, Njegoševa 12, 11000 Belgrade

Scientific Adviser

Ksenija Stojanović, University of Belgrade, Faculty of Chemistry Studentski trg 12-16, 11000 Belgrade

Associate Professor


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