Electrochemical characterisation of novel screen-printed carbon paste electrodes for voltammetric measurements

Main Article Content

Milan Sýs
Elmorsy Khaled
Radovan Metelka
Karel Vytřas

Abstract

This work is focused on the homemade screen-printed carbon paste electrode containing basically graphite powder (or glassy carbon powder), poly(vinylbchloride) (PVC) and paraffin oil. It compares the electrochemical properties of conventional carbon-based electrodes and prepared screen-printed carbon paste electrodes towards [Fe(CN)6]3‑/[Fe(CN)6]4‑ and quinone/hydro­quin­one redox couples. Significant attention is paid to the development of the corresponding carbon inks, printing and the surface characterisation of the resulting electrodes by the scanning electron microscopy. An optimization con­sisted of the selection of the organic solvent, the optimal content of the used polymer with the chosen paste binder, appropriate isolation of electric contact, etc. Very similar properties of the prepared screen-printed electrodes, con­tain­ing only corresponding carbon powder and 3 % PVC, with their conven­tional carbon paste electrode and glassy carbon-based electrodes, were obs­erved during their characterisation. Screen-printed electrodes, with the pasting liquid usually provided satisfactory analytical data. Moreover, they can be used in the flow injection analysis and could undoubtedly replace the carbon paste grooved electrodes. It can be assumed that certain progress in the development of elec­trode materials was achieved by this research.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Article Details

How to Cite
[1]
M. Sýs, E. Khaled, R. Metelka, and K. Vytřas, “Electrochemical characterisation of novel screen-printed carbon paste electrodes for voltammetric measurements”, J. Serb. Chem. Soc., vol. 82, no. 7-8, pp. 865–877, Aug. 2017.
Section
Electrochemistry

References

I. Švancara, K. Kalcher, A, Walcarius, K. Vytřas, Electroanalysis with Carbon Paste Electrodes. CRC Press, Taylor & Francis Group, Boca Raton, FL, 2012

K. Vytřas, I. Švancara, R. Metelka, J. Serb. Chem. Soc. 74 (2009) 1021

I. Švancara, K. Vytřas, J. Barek, J. Zima, Crit. Rev. Anal. Chem. 31 (2001) 311

J. Lindquist, J. Electroanal. Chem. 18 (1968) 204

I. Švancara, K. Vytřas, K. Kalcher, A. Walcarius, J. Wang, Electroanalysis 21 (2009) 7

C. A. H. Chambers, J. K. Lee, J. Electroanal. Chem. 14 (1967) 309

J. Wang, B. A. Freiha, Anal. Chem. 56 (1984) 849

I. Noviandri, R. Rakhmana, Int. J. Electrochem. Sci. 7 (2012) 4479

T. Ch. Huang, L. Ch. Yeh, H. Y. Huang, Z. Y. Nian, Y. Ch. Yeh, Y. Ch. Chou, J. M. Yeh, M. H. Tsaic, Polym. Chem. 5 (2014) 630

I. Švancara, P. Foret, K. Vytřas, Talanta 64 (2004) 844

L. G. Shaidarova, S. A. Ziganshina, G. K. Budnikov, J. Anal. Chem. 58 (2003) 577

J. Labuda, A. Meister, P. Gläser, G. Werner, Fresenius J. Anal. Chem. 360 (1998) 654

M. Portaccio, D. D. Tuoro, F. Arduini, M. Lepore, D. G. Mita, N. Diano, L. Mita, D. Moscone, Biosens. Bioelectron. 25 (2010) 2003

L. Gorton, Electroanal. 7 (1995) 23

J. K. Yang, K. S. Ha, H. S. Baek, S. S. Lee, M. L. Seo, Bull. Korean Chem. Soc. 25 (2004) 1499

P. Fanjul-Bolado, David Hernández-Santos, P. J. Lamas-+Ardisana, A. Martín-Pernía,

A. Costa-García, Electrochim. Acta 53 (2008) 3635

I. Švancara, P. Kotzian, M. Bartoš, K. Vytřas, Electrochem. Commun. 7 (2005) 657

E. Khaled, H. N. A. Hassan, I. H. I. Habib, R. Metelka, Int. J. Electrochem. Sci. 5 (2010) 158

E. Khaled, G. G. Mohamed, T. Awad, Sensors Actuators, B Chem. 135 (2008) 74

T. Mikysek, I. Švancara, K. Kalcher, M. Bartoš, K. Vytřas, J. Ludvík, Anal. Chem. 81 (2009) 6327

I. Švancara, M. Hvízdalová, K. Vytřas, K. Kalcher, R. Novotný, Electroanal. 8 (1996) 61

J. Wang, Ü. A. Kirgöz, J. W. Mo, J. Lu, A. N. Kawde, A. Muck, Electrochem. Commun. 3 (2001) 203

K. Vytřas, V. Dvořáková, I. Zeman, Analyst 114 (1989) 1435

H. A. Yasser, M. H. Al-Maamori, A. I. Al-Mosawi, Res. J. Recent. Sci. 3 (2014) 209

J. P. Metters, R. O. Kadara, C. E. Banks, Analyst 136 (2011) 1067

M. Sýs, S. Žabčíková, L. Červenka, K. Vytřas, Potravinarstvo 11 (2017) 96.