First cobalt complexes with methyl pyruvate semi/thiosemicarbazone – Synthesis, physicochemical and structural characterization

Main Article Content

Marko V. Rodić
http://orcid.org/0000-0002-4471-8001
Vukoslava Miškov-Pajić
Vukadin M. Leovac
Mirjana M. Radanović
https://orcid.org/0000-0001-6675-9763
Ljiljana S. Vojinović-Ješić
https://orcid.org/0000-0002-8618-7819
Svetlana K. Belošević
Željko K. Jaćimović
Vukosava Živković-Radovanović
https://orcid.org/0000-0003-2558-4957

Abstract

In the reaction of acetone solutions of CoX2∙nH2O (X = Cl, Br) with methyl pyruvate semi/thiosemicarbazone (Hmps, Hmpt) the first Co(II) com­plexes with these ligands, i.e., [Co(Hmps)(H2O)X2] (X = Cl (1), Br (2)), [Co(Hmpt)2][CoCl4]∙2H2О (3) and [Co(Hmpt)2]Br2∙Me2CO (4) were obtained. Complexes 1 and 2 represent the first examples of metal complexes of Hmps. All the obtained compounds were characterized by elemental analysis, conduc­to­metry, magnetic measurements, and IR spectra, and for complexes 24, single crystal X-ray diffraction analysis was also performed. The effective magnetic moments were close to the upper limit (5 μB) for complexes 1 and 2, and close to the lower limit (4.4 μB) for complexes 3 and 4, and as such are characteristic for high-spin Co(II) complexes. Structural analysis showed that both ligands coordinate in a neutral form in a tridentate manner, via the ester oxygen, imine nitrogen and the oxygen atom of the ureido (Hmps), or the sul­fur atom of the thioureido group (Hmpt). The central metal atoms are situated in a deformed octahedral coordination environment. Complex 2 has cis-Br con­figuration, while complexes 3 and 4 have mer-configuration.

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How to Cite
[1]
M. V. Rodić, “First cobalt complexes with methyl pyruvate semi/thiosemicarbazone – Synthesis, physicochemical and structural characterization”, J. Serb. Chem. Soc., vol. 85, no. 4, pp. 453–466, Apr. 2020.
Section
Inorganic Chemistry
Author Biography

Marko V. Rodić, University of Novi Sad, Faculty of Sciences, Trg D. Obradovića 3, 21000 Novi Sad

Assistant Professor
Chair of Physical Chemistry

Department of Chemistry, Biochemistry and Environmental Protection
Faculty of Sciences
University of Novi Sad

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