Synthesis, crystal structure and biological activity of copper(II) complex with 4-nitro-3-pyrazolecarboxylic ligand

Milica Kosović, Slađana Novaković, Željko Jaćimović, Nedeljko Latinović, Nada Marković, Tamara Đorđević, Eugen Libowitzky, Gerald Giester

Abstract


Reaction of 4-nitro-3-pyrazolecarboxylic acid and Cu(OAc)2H2O in ethanol resulted in new coordination compound [Cu2(4nitro-3pzc)2(H2O)6]2H2O, (4nitro-3pzc = 4-nitro-3-pyrazolecarboxylate). The compound was investigated by means of single-crystal X-ray diffraction and infrared spectroscopy. Biologi­cal activity of the complex was also tested. In the crystal structure of [Cu2(4nit- -3pzc)2(H2O)6]2H2O, the Cu(II) ion is in a distorted [4+2] octahedral coordination due to the Jan-Teller effect. A survey of the Cambridge Structural Database shows that the octahedral coordination geometry is generally rare for the pyrazole bridged Cu(II) complexes. In the case of Cu(II) complexes with the 3-pyrazole­carboxylato ligands, no complexes with the similar, octahedral coordination geometry have been reported. Biological research based on determining the inhibition effect of commercial fungicide Cabrio top and newly synthesized complex on Ph. viticola have been carried using the phytosanitary method.


Keywords


Pyrazole; Copper; Coordination complexes; Crystal structure; Infrared spectra; Inhibition effect

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DOI: https://doi.org/10.2298/JSC190724133K

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