Determination of tramadol in pharmaceutical forms and urine samples using a boron-doped diamond electrode

Ertuğrul Keskin, Shabnam Allahverdiyeva, Esma Şeyho, Yavuz Yardım

Abstract


The present work describes the electroanalytical investigation and a novel voltammetric method for a cheap, fast and simple quantification of tramadol (TRH) using a boron-doped diamond (BDD) electrode. TRH dis­played one well-defined, irreversible and adsorption-controlled oxidation peak at about +1.58 V (vs. Ag/AgCl) in Britton-Robinson buffer (BR, 0.1 mol L-1, pH 3.0) using cyclic voltammetry (CV) technique. The voltammetric responses of the oxidation peaks are dependent on pH and its sensitivity was significantly enhanced in the existence of surfactant media (sodium dodecyl sulphate, SDS). In optimized experiment conditions, employing square-wave stripping mode, it was found that there was an excellent correlation between oxidation peak current and TRH concentration in the range of 0.25 to 50.0 μg mL-1 (8.34×10-7-1.67×10-4 mol L-1), with a detection limit of 0.072 μg mL-1 (2.40×10-7 mol L-1) in 0.1 mol L-1 BR buffer (pH 3.0) solution comprising 8×10-4 mol L-1 SDS at +1.52 V (after 30 s accumulation at open-circuit condition). The developed approach can be used for the quantification of TRH in the pharmaceutical formulations and the spiked human urine samples with acceptable recoveries.


Keywords


tramadol; boron-doped diamond electrode; pharmaceutical formulation; urine samples; sodium dodecyl sulfate

Full Text:

PDF (1,442 kB)

References


F. Fathirad, A. Mostafavi, D. Afzali, Anal. Chim. Acta 940 (2016) 65–72 (http://dx.doi.org/10.1016/j.aca.2016.08.051).

K. S. Lewis, N. H. Han, Am. J. Heal. Pharm. 54 (1997) 643–652 (http://dx.doi.org/https://doi.org/10.1093/ajhp/54.6.643).

M. M. Foroughi, S. Jahani, H. Hassani Nadiki, Sensors Actuators, B Chem. 285 (2019) 562–570 (http://dx.doi.org/10.1016/j.snb.2019.01.069).

M. Nobilis, J. Kopecký, J. Květina, J. Chládek, Z. Svoboda, V. Voříšek, F. Perlík, M. Pour, J. Kuneš, J. Chromatogr. A 949 (2002) 11–22 (http://dx.doi.org/10.1016/S0021-9673(01)01567-9).

T. Madrakian, A. Afkhami, H. Mahmood-Kashani, M. Ahmadi, Talanta 105 (2013) 255–261 (http://dx.doi.org/10.1016/j.talanta.2012.12.039).

N. A. Ghalwa, H. M. Abu-Shawish, F. R. Zaggout, S. M. Saadeh, A. R. Al-Dalou, A. A. Abou Assi, Arab. J. Chem. 7 (2014) 708–714 (http://dx.doi.org/10.1016/j.arabjc.2010.12.007).

G. Saccomanni, S. Del Carlo, M. Giorgi, C. Manera, A. Saba, M. Macchia, J. Pharm. Biomed. Anal. 53 (2010) 194–199 (http://dx.doi.org/10.1016/j.jpba.2010.03.016).

I. Y. Zaghloul, M. A. Radwan, J. Liq. Chromatogr. Relat. Technol. 20 (1997) 779–787 (http://dx.doi.org/10.1080/10826079708014142).

S. Glavanović, M. Glavanović, V. Tomišić, Spectrochim. Acta - Part A Mol. Biomol. Spectrosc. 157 (2016) 258–264 (http://dx.doi.org/10.1016/j.saa.2015.12.020).

S. N. Ding, J. J. Xu, W. J. Zhang, H. Y. Chen, Talanta 70 (2006) 572–577 (http://dx.doi.org/10.1016/j.talanta.2006.01.017).

V. Gambaro, C. Benvenuti, L. De Ferrari, L. Dell’Acqua, F. Farè, Farmaco 58 (2003) 947–950 (http://dx.doi.org/10.1016/S0014-827X(03)00153-8).

H. M. Abu-Shawish, N. A. Ghalwa, F. R. Zaggout, S. M. Saadeh, A. R. Al-Dalou, A. A. A. Assi, Biochem. Eng. J. 48 (2010) 237–245 (http://dx.doi.org/10.1016/j.bej.2009.10.019).

A. Afkhami, H. Ghaedi, T. Madrakian, M. Ahmadi, H. Mahmood-Kashani, Biosens. Bioelectron. 44 (2013) 34–40 (http://dx.doi.org/10.1016/j.bios.2012.11.030).

S. Chitravathi, N. Munichandraiah, J. Electroanal. Chem. 764 (2016) 93–103 (http://dx.doi.org/10.1016/j.jelechem.2016.01.021).

Y. Yardım, A. Levent, E. Keskin, Z. Şentürk, Talanta 85 (2011) 441–448 (http://dx.doi.org/10.1016/j.talanta.2011.04.005).

S. Pysarevska, L. Dubenska, S. Plotycya, Ľ. Švorc, Sensors Actuators, B Chem. 270 (2018) 9–17 (http://dx.doi.org/10.1016/j.snb.2018.05.012).

Ľ. Švorc, K. Borovská, K. Cinková, D. M. Stanković, A. Planková, Electrochim. Acta 251 (2017) 621–630 (http://dx.doi.org/10.1016/j.electacta.2017.08.077).

Y. Li, J. Hao, G. Li, J. Dispers. Sci. Technol. 27 (2006) 781–787 (http://dx.doi.org/10.1080/01932690500461172).

A. M. Santos, F. C. Vicentini, L. C. S. Figueiredo-Filho, P. B. Deroco, O. Fatibello-Filho, Diam. Relat. Mater. 60 (2015) 1–8 (http://dx.doi.org/10.1016/j.diamond.2015.10.005).

O. Yunusoğlu, S. Allahverdiyeva, Y. Yardım, Z. Şentürk, Electroanalysis (2019) 1–9 (http://dx.doi.org/10.1002/elan.201900452).

M. Soleimani, M. G. Afshar, A. Shafaat, G. A. Crespo, Electroanalysis 25 (2013) 1159–1168 (http://dx.doi.org/10.1002/elan.201200601).

E. Mynttinen, N. Wester, T. Lilius, E. Kalso, J. Koskinen, T. Laurila, Electrochim. Acta 295 (2019) 347–353 (http://dx.doi.org/10.1016/j.electacta.2018.10.148).

S. Y. Al Samarrai, F. M. Abdoon, K. K. Hashim, Microchem. J. 146 (2019) 588–591 (http://dx.doi.org/10.1016/j.microc.2019.01.041).

F. Ghorbani-Bidkorbeh, S. Shahrokhian, A. Mohammadi, R. Dinarvand, Electrochim. Acta 55 (2010) 2752–2759 (http://dx.doi.org/10.1016/j.electacta.2009.12.052).

A. Babaei, A. R. Taheri, M. Afrasiabi, J. Braz. Chem. Soc. 22 (2011) 1549–1558 (http://dx.doi.org/10.1590/S0103-50532011000800020).

B. J. Sanghavi, A. K. Srivastava, Anal. Chim. Acta 706 (2011) 246–254 (http://dx.doi.org/10.1016/j.aca.2011.08.040).

A. Afkhami, H. Khoshsafar, H. Bagheri, T. Madrakian, Anal. Chim. Acta 831 (2014) 50–59 (http://dx.doi.org/10.1016/j.aca.2014.04.061).

B. Deiminiat, G. H. Rounaghi, M. H. Arbab-Zavar, Sensors Actuators, B Chem. 238 (2017) 651–659 (http://dx.doi.org/10.1016/j.snb.2016.07.110).

E. Çidem, T. Teker, M. Aslanoglu, Microchem. J. 147 (2019) 879–885 (http://dx.doi.org/10.1016/j.microc.2019.04.018).

R. Kiran, E. Scorsone, P. Mailley, P. Bergonzo, Anal. Chem. 84 (2012) 10207–10213 (http://dx.doi.org/10.1021/ac301177z).

F. Dönmez, Y. Yardım, Z. Şentürk, Diam. Relat. Mater. 84 (2018) 95–102 (http://dx.doi.org/10.1016/j.diamond.2018.03.013).




DOI: https://doi.org/10.2298/JSC190906138K

Copyright (c) 2019 Journal of the Serbian Chemical Society

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

IMPACT FACTOR 0.828 (140 of 172 journals)
5 Year Impact Factor 0.917 (140 of 172 journals)