Benzimidazole-functionalized fluorescent probe for rapid detection of 2,4,6-trinitrophenol and Ag+ in semiaqueous medium Scientific paper

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Published: Aug 27, 2021
DOI: https://doi.org/10.2298/JSC200702009W
Keywords:
benzimidazole quinoline fluorescence quenching TNP

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Bin Wang
Institute of Chemical Engineering, Anhui University of Science and Technology, Huainan, Anhui, 232001, China; 2Institute of Environmen-Frriendly Materials and Occupational Health of Anhui University of Science and Technology (Wuhu), Wuhu, 241003, China and State Key Laboratory of Mining Response and Disaster Prevention and Control in Deep Coal Mines, Anhui University of Science and Technology, Huainan 232001, China.
Xixi Zuo
Institute of Chemical Engineering, Anhui University of Science and Technology, Huainan, Anhui, 232001, China
Jing Ma
Institute of Chemical Engineering, Anhui University of Science and Technology
https://orcid.org/0000-0003-2873-296X
Xiangmei Ma
Institute of Chemical Engineering, Anhui University of Science and Technology, Huainan, Anhui, 232001, China and Institute of Environment-friendly Materials and Occupational Health of Anhui University of Science and Technology (Wuhu), Wuhu, 241003, China
https://orcid.org/0000-0003-2873-296X

Abstract

In this study, a simple fluorescent chemosensor with good fluore­scence properties was synthesized, and was used to develop a sensitive and selective sensor, for the determination of 2,4,6-trinitrophenol (TNP) and Ag+ in THF/H2O medium, based on the fluorescence quenching mechanism. Fluores­cence quenching experiments revealed that the fluorescence intensities of the resulted probe were linear with the concentrations of TNP and Ag+ in the concentration range of 3.0–5.0 and 2.0–5.0 µmol dm-3, with the detection limit of 1.36 and 0.82 µmol dm-3, respectively. At the same time, accompanied with fluorescent color change under 365 nm UV light irradiation. This has demon­strated that the compound can act as a potential candidate for a "naked-eye" rapidly detector for Ag+ and TNP in soils and aquatic systems.

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[1]
B. Wang, X. Zuo, J. Ma, and X. Ma, “Benzimidazole-functionalized fluorescent probe for rapid detection of 2,4,6-trinitrophenol and Ag+ in semiaqueous medium: Scientific paper”, J. Serb. Chem. Soc., vol. 86, no. 9, pp. 859–870, Aug. 2021.
Issue
Vol. 86 No. 9 (2021)
Section
Analytical Chemistry
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