, Scientific Veterinary Institute of Serbia, Vojvode Toze 14, 11000 Belgrade, Serbia
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Journal of the Serbian Chemical Society Vol. 82 No. 12 (2017) - Polymers
Synthesis, structure and thermogravimetric analysis of alpha,omega-telechelic polydimethylsiloxanes of low molecular weight
Abstract
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Supplementary Material (2,12 MB)
Figure 6_Final
Figure 2_Final
Corrected proof
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Cover Letter_Vesna Antic
Figure 1. Synthesis of α,ω-telechelic PDMS from disiloxane (DS) and D4
Figure 2. The structure of disiloxanes and α,ω-telechelic PDMSs
Figure 3. Structural isomers of DAPTMDS
Figure 4. GPC curves of α,ω-telechelic PDMSs
Figure 5. TG (left panel) and DTG (right panel) curves of α,ω-telechelic PDMSs in nitrogen and air
Figure 6. Thermal degradation of silanol-terminated PDMS – “unzipping†mechanism
Figure 7. Thermal degradation of PDMS - “random scission†mechanism – A) intramolecular redistribution and B) intermolecular redistribution
Figure 8. Thermo-oxidative degradation of PDMS by free-radical mechanism
Supplementary Material: Figure S-1. Calibration curve for GPC
Supplementary Material: Table S-I. Bulk viscosities and calculated molecular weights of PDMS standards
Response to Reviewers_Vesna Antic
Corrected Figure 1. Synthesis of α,ω-telechelic PDMS from disiloxane (DS) and D4
Corrected Figure 2. The structure of disiloxanes and α,ω-telechelic PDMSs
Corrected Figure 3. Inactivation of CER in the presence of DAPTMDS
Corrected Figure 4. Structural isomers of DAPTMDS
Corrected Figure 5. GPC curves of α,ω-telechelic PDMSs
Corrected Figure 6. TG (left panel) and DTG (right panel) curves of α,ω-telechelic PDMSs in nitrogen and air
Corrected Figure 7. Thermal degradation of silanol-terminated PDMS – “unzipping†mechanism
Corrected Figure 8. Thermal degradation of PDMS - “random scission†mechanism – A) intramolecular redistribution and B) intermolecular redistribution
Corrected Figure 9. Thermo-oxidative degradation of PDMS by free-radical mechanism
Corrected Figure 5. GPC curves of α,ω-telechelic PDMSs
Supplementary material: Corrected Figure. S-1. Calibration curve for GPC
Supplementary Material: Figure S-2. 1H NMR spectra of α,ω-telechelic PDMSs
Supplementary Material: Figure S-3. 13C NMR spectra of α,ω-telechelic PDMSs
Supplementary Material: Figure S-4. DEPT spectrum of DAPTMDS
Supplementary Material: Table S-I. Bulk viscosities and calculated molecular weights of PDMS standards
Fig. 5_Corr 1. GPC curves of α,ω-telechelic PDMSs
Fig. 6_Corr 1. TG (left panel) and DTG (right panel) curves of α,ω-telechelic PDMSs in nitrogen and air
Supplementary materials