Spectroscopic and structural characterization of hexaamminecobalt(III) dibromide permanganate Scientific paper

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Published: Dec 25, 2023
Updated: 25.12.2023
DOI: https://doi.org/10.2298/JSC230702062B
Keywords:
permanganate ammine cobalt(III) IR and Raman spectroscopy solid-phase quasi-intramolecular redox reaction

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Berta Barta-Holló
Department of Chemistry, Biochemistry and Environmental Protection, Faculty of Sciences, University of Novi Sad, Trg Dositeja Obradovića 3, 21000 Novi Sad, Serbia
https://orcid.org/0000-0002-5786-442X
Niloofar Bayat
2Institute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Magyar Tudósok krt. 2., H-1117 Budapest, Hungary
https://orcid.org/0009-0008-0682-4402
Laura Bereczki
Centre for Structural Science, Research Centre for Natural Sciences, Magyar Tudósok krt. 2., H-1117 Budapest, Hungary
Vladimir Petrusevski
Faculty of Natural Sciences and Mathematics, Ss. Cyril and Methodius University, Skopje, MK-1000, North Macedonia
https://orcid.org/0000-0002-4796-4929
Kende Attila Béres
György Hevesy PhD School of Chemistry, Institute of Chemistry, ELTE Eötvös Loránd University, Pázmány Péter s. 1/A, H-1117 Budapest, Hungary
https://orcid.org/0000-0003-4257-0581
Attila Farkas
Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Műegyetem rkp. 3., H-1111, Budapest, Hungary
https://orcid.org/0000-0002-8877-2587
Imre Miklós Szilágyi
Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Műegyetem rakpart 3, H-1111 Budapest, Hungary
László Kótai
Research Centre for Natural Sciences, Budapest, Hungary
https://orcid.org/0000-0001-6375-3120

Abstract

Structural and spectroscopic characterization (SXRD, IR, liq. N2 tem­perature Raman, UV) of hexaamminecobalt(III) dibromide permanganate, [Co(NH3)6]Br2(MnO4) (compound 1), are described. There is a 3D hydrogen bond network including N–H···O–Mn and N–H···Br interactions, which could serve as potential reaction centres for solid-phase redox reactions between the ammonia ligands and/or bromide ions as reductants and permanganate ions as oxidant agents. The effect of the nature of halogen ions on the structural and spectroscopic properties of [Co(NH3)6]Br2(MnO4) and the analogous chloride compound, [Co(NH3)6]Cl2(MnO4) (compound 2), are discussed in detail.

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How to Cite
[1]
B. Barta-Holló, “Spectroscopic and structural characterization of hexaamminecobalt(III) dibromide permanganate: Scientific paper”, J. Serb. Chem. Soc., vol. 88, no. 12, pp. 1237–1252, Dec. 2023.
Issue
Vol. 88 No. 12 (2023): Theme issue honoring Professor Vukadin Leovac's 80th birthday
Section
Theme issue honoring Professor Vukadin Leovac's 80th birthday
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