Search for new apatite-like phases for lead utilization based on crystal structure and thermal expansion Scientific paper

Main Article Content

Evgeny Bulanov
https://orcid.org/0000-0001-9162-9602
Anastasyya Vasileva
Oxana Golitsyna
Alyona Shvareva
Alexander Knyazev
https://orcid.org/0000-0002-2880-3484

Abstract

Apatites, being one of the most numerous mineral-like families of compounds, are considered as a matrix for binding lead ions, which is dan­gerous for the biosphere. The crystal-chemical (composition, structure) and thermophysical aspects (thermal expansion) are considered as the basis for ana­lysing the properties of this kind of material. It is suggested that substances of the composition Pb5(AIVO4)2(BVIO4), Pb5(AIVO4)(CVO4)2 can be a perspective form of lead binding materials based on compounds with the structure of apa­tite (AIV = Si, Ge; BVI = S, Cr; CV = P). Such compounds, as it was shown by DTA and HTXRD experiments, are distinguished by the absence of polymer­phism and the abnormal ordering of structure. Also, they have relatively low values of thermophysical indicators (the rate of change of linear thermal expan­sion coefficients is 0.02-0.03∙106 K-1; values of the volume thermal expansion coefficients are 40–70×106 K-1). Compounds Pb5(SiO4)(PO4)2 (a = 9.78782(16) Å, c = 7.31084(16) Å, V = 606.555(23) Å3, R-bragg = 4.694 %) and Pb5(GeO4)(PO4)2 (a = 9.87697(12) Å, c = 7.33136(11) Å, V = 619.388(17) Å3, R-bragg = 1.730 %) were obtained, identified and crystallographically characterized for the first time.

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How to Cite
[1]
E. Bulanov, A. . Vasileva, O. . Golitsyna, A. . Shvareva, and A. . Knyazev, “Search for new apatite-like phases for lead utilization based on crystal structure and thermal expansion: Scientific paper”, J. Serb. Chem. Soc., vol. 89, no. 3, pp. 415–428, Apr. 2024.
Section
Materials
Author Biographies

Anastasyya Vasileva, Lobachevsky University, 23 Gagarin ave, Nizhny Novgorod, Russia 603022

PhD-student of the Department of Analytical and Medical Chemistry

Oxana Golitsyna, Lobachevsky University, 23 Gagarin ave, Nizhny Novgorod, Russia 603022

PhD-student of the Department of Analytical and Medical Chemistry

Alyona Shvareva , Lobachevsky University, 23 Gagarin ave, Nizhny Novgorod, Russia 603022

PhD in Inorganic Chemistry, Research Fellow of the Department of Analytical and Medical Chemistry

Alexander Knyazev, Lobachevsky University, 23 Gagarin ave, Nizhny Novgorod, Russia 603022

DSc in Inorganic Chemistry, Professor, Head of the Department of Analytical and Medical Chemistry

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