Modelling a cyclic staircase voltammetry of two electron transfers coupled by a chemical reaction on a rotating disk electrode
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Abstract
Two electrode reactions that are coupled by a chemical reaction are called an ECE mechanism. The model of this mechanism having unstable intermediate is developed for staircase voltammetry on the rotating disk electrode. It is assumed that both electrode reactions are fast and reversible and that the chemical reaction may appear being of the second order and reversible. The influence of the concentration of electro-inactive component of the chemical reaction is investigated and the conditions under which the reaction turns into the first order one and becomes totally irreversible are reported.
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References
R. S. Nicholson, I. Shain, Anal. Chem. 37 (1965) 190 (https://doi.org/10.1021/ac60221a003)
G. S. Alberts, I. Shain, Anal. Chem. 35 (1963) 1859 (https://doi.org/10.1021/ac60205a019)
Š. Komorsky-Lovrić, M. Lovrić, Collect. Czech. Chem. Commun. 72 (2007) 1398 (https://doi.org/10.1135/cccc20071398)
P. Sanecki, K. Kaczmarski, J. Electroanal. Chem. 471 (1999) 14 (https://doi.org/10.1016/S0022-0728(99)00243-0)
P. Sanecki, P. Skital, K. Kaczmarski, Electroanalysis 18 (2006) 981 (https://doi.org/10.1002/elan.200603487)
S. W. Feldberg, Lj. Jeftić, J. Phys. Chem. 76 (1972) 2439 (https://doi.org/10.1021/j100661a017)
G. J. Wilson, C. Y. Lin, R. D. Webster, J. Phys. Chem. B 110 (2006) 11540 (https://doi.org/10.1021/jp0604802)
R. N. Adams, M. D. Hawley, S. W. Feldberg, J. Phys. Chem. 71 (1967) 851 (https://doi.org/10.1021/j100863a011)
D. Nematollahi, S. M. Golabi, J. Electroanal. Chem. 481 (2000) 208 (https://doi.org/10.1016/S0022-0728(99)00500-8)
Y. Li, M. Liu, C. Xiang, Q. Xie, S. Yao, Thin Solid Films 497 (2006) 270 (https://doi.org/10.1016/j.tsf.2005.10.048)
P. T. Sanecki, C. Amatore, P. M. Skital, J. Electroanal. Chem. 546 (2003) 109 ()https://doi.org/10.1016/S0022-0728(03)00138-4
P. T. Sanecki, P. M. Skital, Electrochim. Acta 53 (2008) 7711 (https://doi.org/10.1016/j.electacta.2008.05.023)
R. Gulaboski, V. Mirčeski, I. Bogeski, M. Hoth, J. Solid State Electrochem. 16 (2012) 2315 (https://doi.org/10.1007/s10008-011-1397-5)
S. O. Engblom, J. C. Myland, K. B. Oldham, Anal. Chem. 66 (1994) 3182 (https://doi.org/10.1021/ac00091a029)
M. D. Hawley, S. W. Feldberg, J. Phys. Chem. 70 (1966) 3459 (https://doi.org/10.1021/j100883a015)
C. Amatore, J. M. Saveant, J. Electroanal. Chem. 86 (1978) 227 (https://doi.org/10.1016/S0022-0728(78)80371-4)
J. Galvez, A. Molina, R. Saura, F. Martinez, J. Electroanal. Chem. 127 (1981) 17 (https://doi.org/10.1016/S0022-0728(81)80464-0)
B. Kastening, Anal. Chem. 41 (1969) 1142 (https://doi.org/10.1021/ac60277a016)
H. R. Sobel, D. E. Smith, J. Electroanal. Chem. 26 (1970) 271 (https://doi.org/10.1016/S0022-0728(70)80310-2)
M. Mastragostino, L. Nadjo, J. M. Saveant, Electrochim. Acta 13 (1968) 721 (https://doi.org/10.1016/0013-4686(68)85007-8)
C. Amatore, J. M. Saveant, J. Electroanal. Chem. 85 (1977) 27 (https://doi.org/10.1016/S0022-0728(77)80150-2)
R. S. Nicholson, I. Shain, Anal. Chem. 37 (1965) 178 (https://doi.org/10.1021/ac60221a002)
M. A. Mann, J. C. Helfrick Jr, L. A. Bottomley, J. Electrochem. Soc. 163 (2016) H3101 (http://dx.doi.org/10.1149/2.0151604jes)
A. B. Miles, R. G. Compton, J. Electroanal. Chem. 499 (2001) 1 (https://doi.org/10.1016/S0022-0728(00)00460-5)
J. J. O'Dea, K. Wikiel, J. Osteryoung, J. Phys. Chem. 94 (1990) 3628 (https://doi.org/10.1021/j100372a049)
A. B. Miles, R. G. Compton, J. Phys. Chem. B 104 (2000) 5331 (https://doi.org/10.1021/jp0006882)
Š. Komorsky-Lovrić, M. Lovrić, To Chem. J. 2 (2019) 142 (http://purkh.com/index.php/tochem)
R. Gulaboski, V. Markovski, Zh. Jihe, J. Solid State Electrochem. 20 (2016) 3229 (https://doi.org/10.1007/s10008-016-3230-7)
E. Laborda, J. M. Gomez-Gil, A. Molina, Phys. Chem. Chem. Phys. 19 (2017) 16464 (https://doi.org/10.1039/c7cp02135f)
C. Batchelor-McAuley, Q. Li, S. M. Dapin, R. G. Compton, J. Phys. Chem. B 114 (2010) 4094 (https://doi.org/10.1021/jp1008187)
D. Menshykau, C. Batchelor-McAuley, R. G. Compton, J. Electroanal. Chem. 651 (2011) 118 (https://doi.org/10.1016/j.jelechem.2010.11.024)
G. J. Wilson, C. Y. Lin, R. D. Webster, J. Phys. Chem. B 110 (2006) 11540 (https://doi.org/10.1021/jp0604802)
H.Balslev, D. Britz, Acta Chem. Scand. 46 (1992) 949
R. Saravanakumar, P. Pirabaharan, L. Rajendran, Electrochim. Acta 313 (2019) 441 (https://doi.org/10.1016/j.electacta.2019.05.033)
X. Y. Liu, Y. P. Liu, Z. W. Wu, Thermal Sci. 26 (2022) 2459 (https://doi.org/10.2298/TSCI2203459L)
R. Umadevi, J. Visuvasam, K. Venugopal, L. Rajendran, 1st Int. Conf. Math. Tech. Appl. AIP Conf. Proc. 2277 (2020) 130013 (https://doi.org/10.1063/5.0025822)
M. Lovrić, Turk. J. Chem. 46 (2022) 1226 (https://doi.org/10.55730/1300-0527.3429)
J. Strutwolf, W. W. Schoeller, Electroanalysis 8 (1996) 1034 (https://doi.org/10.1002/elan.1140081111)
M. Lovrić, J. Serb. Chem. Soc. 53 (1988) 211. (UDC 543.47; JSCS-1344).