Synthesis and characterization of nano Fe2CuAl2O7 as a reusable catalyst for Biginelli reaction

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Published: Jan 14, 2025
DOI: https://doi.org/10.2298/JSC240808006К
Keywords:
sol-gel auto-combustion mixed metal oxides BET nanocatalyst one-pot synthesis

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Marzieh M. Keshtiban
Payame Noor University
https://orcid.org/0009-0002-7064-3477
Abbas Nikoo
Shahid Bakeri High Education Center, Urmia University, Urmia, Iran
https://orcid.org/0000-0002-0021-7475
Bakhshali Massoumi
Payame Noor University
https://orcid.org/0000-0002-7720-2677

Abstract

In this research, novel mixed metal oxide nanoparticles (NPs) Fe2CuAl2O7 were synthesized by applying sol-gel auto-combustion method. The Fe2CuAl2O7 NPs were identified by XRD, FT-IR, Mapping and EDS. The XRD pattern showed that Fe2CuAl2O7 NPs contain a crystalline structure and have just one phase, and types of crystals are FCC. The size distribution of Fe2CuAl2O7 NPs was determined by FESEM to be about 41.44 nm. Using the BET equation, the surface area of Fe2CuAl2O7 NPs was calculated as 26.174 m2 g-1. Fe2CuAl2O7 NPs were used as a catalyst for the Biginelli reaction. 3,4-dihydropyrimidine-2(1H)-one/thione derivatives were prepared in the presence of Fe2CuAl2O7 nanocatalyst with short time and 75-97 % efficiency in water. In addition, recovery and reuse of Fe2CuAl2O7 nanocatalyst was done up to five times without significant change in catalytic ability.

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[1]
M. M. Keshtiban, A. Nikoo, and B. Massoumi, “Synthesis and characterization of nano Fe2CuAl2O7 as a reusable catalyst for Biginelli reaction”, J. Serb. Chem. Soc., Jan. 2025.
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