Kinetics and mechanism of the oxidation of dithiocarbamic acids in the presence of Co(II) phthalocyaninetetacarboxylic acid

Artur Vashurin, Ilya Kuzmin, Vladimir Mayzlish, Mikhail Razumov, Oleg Golubchikov, Oscar Koifman

Abstract


The present work contains kinetic data of the oxidation of sodium diethyldithiocarbamate in the presence of phthalocyanine catalysts. It is shown that the nature of the peripheral substituent has a great influence on the self-
-association of phthalocyanines and on their catalytic activity. A mechanism of the oxidation of sodium diethyldithiocarbamate involving the formation of a triple complex of the substrate, the reduced form of the catalyst and oxygen is offered. It is also shown that the oxidation mechanism of dithiocarbamic acids is different from that for cysteine.


Keywords


Co(II)phthalocyanines; catalysts; oxidation; kinetics; mechanism

References


A. B. Sorokin, Chem. Rev. 113 (2013) 8152

B. Basu, S. Satapathy, A. K. Bhatnagar, Catal. Rev. 35 (1993) 571

A. Shaabani, K. Keshipour, M. Hamidzad, S. Shaabani, J. Mol. Catal., A: Chem. 395 (2014) 494

M. Mirzaeian, A. M. Rashidi, M. Zare, R. Ghabezi, J. Nat. Gas Sci. Eng. 18 (2014) 439

Z. Huang, H. Bao, Y. Yao, W. Lu, W. Chen, Appl. Catal., B 154–155 (2014) 36

T. Billard, B. R. Langlois, S. Large, D. Anker, N. Roidot, P. Roure, J. Org. Chem. 61 (1996) 7545

B. Banerjee, S. N. Chakravarty, B. V. Kamath, A. B. Biswas, J. Appl. Polym. Sci. 24 (2003) 683

E. M .Tyapochkin, E. I. Kozliak, J. Mol. Catal., A: Chem. 242 (2005) 1

G. Das, B. Sain, S. Kumar, Catal. Today 198 (2012) 228

J. C. Bricker, L. Laricchia, Top. Catal. 55 (2012) 1315

N. Lebedeva, N. Pavlycheva, O. Petrova, A. Vyugin, A. Kinchin, E. Parfenyuk, V. Mayzhlish, G. Shaposhnikov, Mendeleev Commun. 13 (2003) 237

A. W. Snow, in The Porphyrin Handbook. Phthalocyanines: Properties and Materials, K. M. Kadish, K. M. Smith, R. Guilard, Eds., Elsevier Science, Amsterdam, 2003, Ch. 17

A. A. Voronina, I. A. Kuzmin, A. S. Vashurin, G. P. Shaposhnikov, S. G. Pukhovskaya, O. A. Golubchikov, Russ. J. Gen. Chem. 84 (2014) 1777

M. R. Hoffmann, B. C. Lim, Environ. Sci. Technol. 13 (1979) 1406

M. R. Hoffmann, A. P. Hong, Sci. Total Environ. 64 (1987) 90

P.-S. K. Leung, M. R. Hoffmann, J. Phys. Chem. 93 (1989) 434

A. Andreev, V. Ivanova, L. Prahov, I. D. Schopov, J. Mol. Catal., A: Chem. 95 (1995) 197

H. Fischer, G. Shulz-Ekloff, D. Wörle, Chem. Eng. Technol. 20 (1997) 624

H. Fischer, G. Shulz-Ekloff, D. Wörle, Chem. Eng. Technol. 20 (1997) 462

S. A. Borisenkova, Pet. Chem. 31 (1991) 391

A. Vashurin, V. Maizlish, S. Pukhovskaya, A. Voronina, I. Kuzmin, N. Futerman, O. Golubchikov, O. Koifman, J. Porphyrins Phthalocyanines 19 (2015) 573

M. Hassanein, M. Abdo, S. Gerges, S. El-Khalafy, J. Mol. Catal., A: Chem. 287 (2008) 53

V. Iliev, A. Ilieva, J. Mol. Catal., A: Chem. 103 (1995) 147

V. Iliev, A. Ilieva, L. Bilyarska, J. Mol. Catal., A: Chem. 137 (1999) 15

N. Kuznetsova, N. Gretsova, V. Derkacheva, O. Kaliya, E. Lukyanets, J. Porphyrins Phthalocyanines 7 (2003) 147

A. S. Vashurin, S. G. Pukhovskaya, A. S. Semeikin, O. A. Golubchikov, Macro¬hetero-cycles 5 (2012) 72

W. J. Schutte, M. Sluyters-Rehbach, J. H. Sluyters, J. Phys. Chem. 97 (1993) 6069

E. V. Kudrik, S. V. Makarov, A. Zahl, R. van Eldik, Inorg. Chem. 42 (2003) 618

B. D. Berezin, Coordination compounds of porphyrins and phthalocyanines, Wiley, New York, 1981

J. K. Joseph, S. L. Jain, B. Sain, Ind. Eng. Chem. Res. 49 (2010) 6674

A. Voronina, I. Kuzmin, A. Vashurin, S. Pukhovskaya, N. Futerman, M. Shepelev, Eur. Chem. Bull. 3 (2014) 187

P.-S. K. Leung, M. R. Hoffmann, Environ. Sci. Tehnol. 22 (1988) 275

E. I. Kozlyak, A. S. Erokhin, A. K. Yatsimirski, React. Kinet. Catal. Lett. 33 (1987) 113

A. S Dubrovina, A. I. Malkova, L. M. Artem'eva, V. I. Tupikov, Russ. J. Phys. Chem. 62 (1988) 1904

D. M. Wagnerová, E. Schwertnerová, J. Vepřek-Šiška, Collect. Czech. Chem. Commun. 39 (1974) 1980

T. A. Fjellstedt, J. Schlesselman, J. Anal. Biochem. 80 (1977) 224

M. R. Ehsani, P. Mirjani, Al. Safadoost, Int. J. Chem. React. Eng. 11 (2013) 431.




DOI: https://doi.org/10.2298/JSC160105048V

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