Environmentally benign copper nanoparticles supported on walnut shell as a highly durable nanocatalyst for the synthesis of propargylamines

Authors

  • Fariba Saadati Department of Chemistry, Faculty of Science, University of Zanjan, P.O. Box 45195-313, Zanjan
  • Vahid Leghaei Department of Chemistry, Faculty of Science, University of Zanjan, P.O. Box 45195-313, Zanjan
  • Asghar Zamani Department of Nanotechnology, Faculty of Science, Urmia University, Urmia

DOI:

https://doi.org/10.2298/JSC161221081S

Keywords:

walnut shell, nanoparticles, reused material, copper, propargylamine

Abstract

This study was an attempt to prepare copper nanoparticles and to determine their catalytic activity employing walnut shell (WS) residue as a green support and a reusable material. The nanocatalyst was characterized though inductively coupled plasma optical emission spectrometry (ICP-OES), N2-sorp­tion analysis, X-ray powder diffraction (XRD), energy-dispersive X-ray spec­troscopy (EDS), and transmission electron microscopy (TEM). The catalytic performance of CuNPs@WS was then studied in the preparation of propargyl­amines via a three-component reaction. The catalyst could be recovered and reused without a significant decrease in its activity over eight reaction cycles. The simple methodology described herein is an economic, ecofriendly and practical method accompanied by higher yields.

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Published

2017-12-03

How to Cite

[1]
F. Saadati, V. Leghaei, and A. Zamani, “Environmentally benign copper nanoparticles supported on walnut shell as a highly durable nanocatalyst for the synthesis of propargylamines”, J. Serb. Chem. Soc., vol. 82, no. 11, pp. 1211-1221, Dec. 2017.

Issue

Section

Organic Chemistry