Comparative mineralization of Basic Red 18 with electrochemical advanced oxidation processes

Main Article Content

Belgin Gozmen
Ozgur Sonmez
Azize Sozutek

Abstract

In this study, the role of electrochemical oxidation processes, inc­luding the electro-Fenton, the electro-persulfate (PS), and the electro/FeII/PS pro­cesses, in the removal of Basic Red 18 (BR18) from aqueous solutions was investigated. It was found that the electro-PS process successfully removes col­our, but after 5 h, it produced only 75 % mineralization. In the same conditions, more effective mineralization was achieved by the electro/FeII/PS process than by the electro-Fenton method. At pH levels of 3.0 and 5.7, very effective min­eral­ization results were produced by the electro/FeII/PS process. Moreover, the maximum mineralization current efficiency values were obtained by the elec­tro/FeII/PS process. The mineralization efficiency of the electro/FeII/PS pro­cess was determined to be 97 % under the following conditions: BR18 initial dye concentration of 100 mg L-1, pH of 5.7, contact time of 5 h, PS concen­tration of 10 mM, Fe2+ concentration of 0.2 mM, and a sodium sulfate concen­tration of 0.05 M.

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How to Cite
[1]
B. Gozmen, O. Sonmez, and A. Sozutek, “Comparative mineralization of Basic Red 18 with electrochemical advanced oxidation processes”, J. Serb. Chem. Soc., vol. 83, no. 1, pp. 93–105, Feb. 2018.
Section
Environmental Chemistry
Author Biography

Belgin Gozmen, Department of Chemistry, Arts and Science Faculty, Mersin University

Chemistry Department

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