Density, viscosity, ultrasonic velocity and excess thermodynamic parameters of ternary liquid mixtures of morpholine + 1,4-dioxane + toluene or nitrobenzene at 308.15 K (Short communication)

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Krishnamoorthy Umasivakami
Vaideeswaran Sundararajan
http://orcid.org/0000-0002-8873-7773
Ambrose Rosevenis

Abstract

Densities, viscosities and ultrasonic velocities were measured for the two ternary liquid mixtures containing morpholine (1) + 1,4-dioxane (2) + nitro­benzene (3) or + toluene (3) at 308.15 K over the entire range of mole fractions. Thermodynamic parameters, such as excess volume (VE), deviations in adiabatic compressibility (ΔKS), free length (ΔLF), isothermal compressibility (ΔβT), free volume (ΔVF) and viscosity (Δh) were calculated and applied to the Red­lich−Kister polynomial equation to determine the appropriate coefficients. The deviations of the ternary liquid mixtures from their ideal behaviour were deter­mined from the measured and calculated thermodynamic properties. In addition, an insight into the molecular structure and possible interactions for the inves­tigated mixtures was attempted.

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How to Cite
[1]
K. Umasivakami, V. Sundararajan, and A. Rosevenis, “Density, viscosity, ultrasonic velocity and excess thermodynamic parameters of ternary liquid mixtures of morpholine + 1,4-dioxane + toluene or nitrobenzene at 308.15 K (Short communication)”, J. Serb. Chem. Soc., vol. 83, no. 10, pp. 1131–1142, Oct. 2018.
Section
Thermodynamics

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