Solid–solid synthesis, characterization and thermal decomposition of a homodinuclear cobalt(II) complex

Abstract

The homodinuclear cobalt(II) complex [Co2(dipic)2(H2O)5]·2H2O was synthesized using pyridine-2,6-dicarboxylic acid (H2dipic) and cobalt(II) acetate as raw materials by room temperature solid–solid reaction. The com­plex was characterized by elemental analyses, single crystal X-ray diffraction, X-ray powder diffraction, Fourier transform infrared spectroscopy, UV spec­troscopy, thermogravimetry and differential scanning calorimetry. Its crystal structure belongs to monoclinic system and space group P2(1)/c. There are two types of six-coordinated Co(II) ions, one Co(II) is coordinated by four carboxyl O atoms and two pyridine N atoms from two dipic2- anions, and another Co(II) is coordinated by five O atoms from five H2O molecules and one bridged carboxyl O atom from the dipic2- anion. The possible pyrolysis reactions in the thermal decomposition processes of the complex, the experimental and calcul­ated percentage mass loss are also given.