Improving the synthesis process of tribological materials based on tin sulphides by adding graphite as additive

Nataša Gajić, Željko Kamberović, Zoran Anđić, Marija Korać, Jarmila Trpčevska, Mirko Stamatović


The aim of this research was to study the effect of graphite addition in the process of synthesis of tribological materials based on tin sulphides. The tin sulphides powders were synthesized from selected precursors by pyrometallurgical method in rotary tilting tube furnace. The thermodynamic parameters of the synthesis were determined using HSC Chemistry software modelling package. In addition, the synthesis process was also characterized by thermal analysis method: Simultaneous Differential Scanning Calorimetry and Thermogravimetry (DCS-TGA). The characterization of the synthesized tin sulphides powders included analysis of chemical composition by optical emission spectroscopy, phase com­position identification by X-ray diffraction (XRD) and examination of morphology, as well as elemental composition by Scanning Electron Microscopy (SEM) with Energy-Dispersive Spectroscopy (EDS). The hexagonal SnS2 and orthorhombic Sn2S3 phases were formed after thermal treatment of starting powders in nitrogen atmosphere. The obtained results indicate the positive effects of the graphite addition which enables synthesis of tin sulphide powders with appropriate content of sulphide phases with minimal loss of sulphur.


tribology; tin sulphide; graphite; pyrometallurgical method

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B. Bhushan, Modern tribology handbook, CRC Press, Boca Raton, 2001 (

X. Xiao, Y. Yin, J. Bao, L. Lu and X. Feng, Adv. Mech. Eng. 8 (2016) 1 (

S. Kim, Int. J. Miner.Metall.Mater. 21 (2014) 95 (

Z. Veličković, N. Ivanković, V. Striković, R. Karkalić, D. Jovanović, Z. Bajić, , J. Bogdanov, J. Serb. Chem. Soc. 81 (2016) 947 (

A.M. Martinez, J. Echeberria, A. Di Loreto, M. Zanon, I. Rampin in Proceedings of the EuroBrake Conference, (2014), Lille, France, Proceedings - EuroBrake 2014, FISITA, London, 2014, p. 1

X. Wu, S. J. Cobbina, G. Mao, H. Xu, Z. Zhang, L. Yang, Environ. Sci. Pollut. Res. 23 (2016) 8244 (

P. B. Tchounwou, C. G. Yedjou, A. K. Patlolla, and D. J. Sutton, Molecular, Clinical and Environmental Toxicology, Springer Basel, Heidelberg, 2012, p. 133.

( 10.1007/978-3-7643-8340-4)

W. Österle and A. I. Dmitriev, Lubricants 4 (2016) 5 (

M. Morbach, H.G. Paul, P. Severit, Systematic approach for structured product development of copper free friction materials, in Proceedings of the EuroBrake Conference, (2012), Dresden, Germany, Proceedings - EuroBrake 2012, FISITA, London, 2012

S. Copelli, A. Fumagalli, L. Gigante, C. Pasturemzi, Powder Technol. 311 (2017) 416 (

K. R. Nandanapalli, D. Mudusu, Crit. Rev. Solid State Mater. Sci. 40 (2015) 359 (

K.T Ramakrishna Reddy, P. Purandhara Reddy, Mater. Lett. 56 (2002) 108 (

S. Suresh, Int. J. of Physical Sciences 9 (2014) 380 (

D. Fister, U. S. Patent No. 5,894,016 A (1999)

B. E. Kinsman, R. Hanney, U. S. Patent No. 6,303,097 B1 (2001)

D. Guhl, V. von Drach, U. S. Patent No. 6,187,281 B1 (2001)

C. Manoharan, G. Kiruthigaa, S. Dhanapandian, K. Santhosh Kuma, M. Jothibas in Proceedings of the International Conference on Advanced Nanomaterials & Emerging Engineering Technologies, (2013), Chennai, India, 2013 International Conference on Advanced Nanomaterials and Emerging Engineering Technologies (ICANMEET 2013), IEEE, New York, 2013, p. 30

Ž. Kamberović, Z. Anđić, M. Korać, M. Gavrilovski, A. Mihajlović, N. Jovanović, N. Gajić, Synthesis of environmentally friendly multipurpose metal sulfide tribological materials, in Proceedings of the International October Conference on Mining and Metallurgy, (2015), Bor, Serbia, 47th International October Conference on Mining and Metallurgy (IOC 2015), Mining and Metallurgy Institute, Bor, 2015, p. 331

M. Kamkui, S. Laminsi, D. Njopwou , T. Djove, Chalcogenide Lett. 11 (2014) p. 219

C. Kaito, Y. Saito, K. Fujita, J. Cryst. Growth 94 (1989) 967


A. Senatore, M. Sarno, P. Ciambelli, Contemporary Materials 6 (2015) 1 (

Roine A. (2006) HSC Chemistry Software® v 6.12, Outotec Research Oy Center, Pori, Finland

B. Meyer, Chem. Rev. 76 (1976) 283 (


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