Room temperature cloud point extraction: An application to preconcentration and spectrophotometric determination of copper(II) - Short communication

Main Article Content

Denys Snigur
http://orcid.org/0000-0002-4183-0321
Alexander Chebotarev
Vitaliy Dubovyi
Dmytro Barbalat
Anastasiia Klochkova

Abstract

The novel cloud point extraction procedure for preconcentration of copper(II) was discovered. A simple chemical method for initiating the cloud point extraction (CPE) has been proposed. The formation of surfactant rich phase in a system containing a nonionic surfactant Triton X-100, copper(II), 6,7-dihydroxy-4-methyl-2-phenylbenzopyrilium chloride (DHMPhB) and ammonium benzoate is observed immediately upon the sulfuric acid addition into solution. Under the optimal conditions (absorption band maximum was 540 nm, concentration 1.5×10-4 mol dm‑3 of DHMPhB, 1.0 vol.% of Triton X-100, 2.0 cm3 of 0.75 mol dm-3 ammonium benzoate, and 1.0 cm3 of 0.5 mol dm-3 sulfuric acid solution for obtaining benzoic–benzoate buffer solution with pH 4.5 and initiation immediate surfactant rich phase formation) the calibration plot for spectrophotometric determination of copper(II) was linear in the range of copper(II) concentration 0.02–0.95 µg cm−3. The limit of detection was cal­culated 0.006 µg cm−3. The water samples were analyzed according to a sug­gested procedure with satisfactory results.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Article Details

How to Cite
[1]
D. Snigur, A. Chebotarev, V. Dubovyi, D. Barbalat, and A. Klochkova, “Room temperature cloud point extraction: An application to preconcentration and spectrophotometric determination of copper(II) - Short communication”, J. Serb. Chem. Soc., vol. 85, no. 1, pp. 89–96, Feb. 2020.
Section
Analytical Chemistry

References

N. Kushchevskaya, A. Gorbachevskii, V. Doroshchuk, S. Kulichenko, J. Water Chem. Technol. 30 (2008) 296 (https://doi.org/10.3103/S1063455X08050068)

P. Samaddar, K. Sen, J. Ind. Eng. Chem. 20 (2014) 1209 (https://doi.org/10.1016/j.jiec.2013.10.033)

M. de Almeida Bezerra, M. A. Z. Arruda, S. L. C. Ferreira, Appl. Spectrosc. Rev. 40 (2005) 269 (https://doi.org/10.1080/05704920500230880)

C. Ojeda, F. Rojas, Microchim. Acta 177 (2012) 1 (https://doi.org/10.1007/s00604-011-0717-x)

K. Simitchiev, V. Stefanova, V. Kmetov, G. Andreev, N. Kovachev, A. Canals, J. Anal. Atom. Spectrom. 23 (2008) 717 (https://doi.org/10.1039/B715133K)

T. Stefanova-Bahchevanska, N. Milcheva, S. Zaruba, V. Andruch, V. Delchev, K. Simitchiev, K. Gavazov, J. Mol. Liquids 248 (2017) 135 (https://doi.org/10.1016/j.molliq.2017.10.046)

R. Gürkan, S. Korkmaz, N. Altunay, Talanta 155 (2016) 38 (https://doi.org/10.1016/j.talanta.2016.04.012)

X. Tang, D. Zhu, W. Huai, W. Zhang, C. Fu, X. Xie, S. Quan, H. Fan, Sep. Purif. Technol. 175 (2017) 266 (https://doi.org/10.1016/j.seppur.2016.11.038)

Q. Xia, Y. Yang, M. Liu, Spectrosc. Lett. 47 (2014) 206 (https://doi.org/10.1080/00387010.2013.790063)

E. Ghasemi, M. Kaykhaii, Anal. Sci. 31 (2015) 407 (https://doi.org/10.2116/analsci.31.407)

N. Sato, M. Mori, H. Itabashi, Talanta 117 (2013) 376 (https://doi.org/10.1016/j.talanta.2013.08.025)

J. Emsley, Natures building blocks: an AZ guide to the elements, Oxford University Press, New York, 2011, p. 720

E. C. de Oliveira, M. I. Monteiro, F. V. Pontes, M. D. de Almeida, M. C. Carneiro, L. I. da Silva, A. AlcoverNeto, J. AOAC Int. 95 (2012) 560

M. Ganjali, M. Pourjavid, L. Babaei, M. Salavati-Niasari, Quím. Nova 27 (2004) 213 (https://doi.org/10.1590/S0100-40422004000200008)

Z. Marchenko, M. Baltsezhak, Methods of spectrophotometry in UV and visual regions in Inorganic Analysis, BINOM Laboratoriyaznanii, Moscow, 2007, p. 712

M. Pesavento, G. Alberti, R. Biesuz, Anal. Chim. Acta 631 (2009) 129 (https://doi.org/10.1016/j.aca.2008.10.046)

V. M. Ivanov, G.A. Kochelaeva, Moscow University Chem. Bull. 42 (2001) 103

D. Citak, M. Tuzen, Food Chem. Toxicol. 48 (2010) 1399 (https://doi.org/10.1016/j.fct.2010.03.008)

G. Khayatian, M. Hashemi, S. Hassanpoor, Indian J. Chem. Tech. 22 (2015) 338

S. Kulichenko, V. Doroschuk, S. Lelyushok, Talanta 59 (2003) 767 (https://doi.org/10.1016/S0039-9140(02)00617-3)

D. Snigur, A. Chebotarev, K. Bevziuk, Moscow University Chem. Bull. 72 (2017) 187 (https://doi.org/10.3103/S0027131417040095)

A. Chebotarev, V. Dubovyi, A. Demchuk, A. Klochkova, D. Snigur, Ukr. Chem. J. 84 (2018) 1

L. J. Manzoori, G. Karim-Nezhad, Iran. J. Chem. Chem. Eng. 24 (2005) 47

P. Liang, J. Yang, J. Food Compos. Anal. 23 (2010) 95 (https://doi.org/10.1016/j.jfca.2009.01.015)

S. Nohut, S. Karabocek, S. Güner, Y. Gok, J. Pharm. Biomed. Anal. 20 (1999) 309 (https://doi.org/10.1016/S0731-7085(99)00045-X).