Photodegradation of selected pesticides: Photocatalytic activity of bare and PANI-modified TiO2 under simulated solar irradiation

Marina J. Lazarević; Vesna N. Despotović; Daniela V. Šojić Merkulov; Nemanja D. Banić; Nina L. Finčur; Dragana D. Četojević-Simin; Mirjana I. Čomor; Biljana F Abramović

doi:10.2298/JSC190301083L

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Published: Jan 10, 2020

DOI: https://doi.org/10.2298/JSC190301083L

Keywords:

pesticides bare TiO2 nanoparticle TiO2/polyaniline nanocomposite cytotoxicity environmental waters radical hole and electron scavengers

Marina J. Lazarević

University of Novi Sad Faculty of Sciences, Department of Chemistry, Biochemistry and Environmental Protection, Trg D. Obradovića 3, 21000 Novi Sad

http://orcid.org/0000-0002-9539-4588

Vesna N. Despotović

University of Novi Sad Faculty of Sciences, Department of Chemistry, Biochemistry and Environmental Protection, Trg D. Obradovića 3, 21000 Novi Sad

Daniela V. Šojić Merkulov

University of Novi Sad Faculty of Sciences, Department of Chemistry, Biochemistry and Environmental Protection, Trg D. Obradovića 3, 21000 Novi Sad

http://orcid.org/0000-0003-4504-291X

Nemanja D. Banić

University of Novi Sad Faculty of Sciences, Department of Chemistry, Biochemistry and Environmental Protection, Trg D. Obradovića 3, 21000 Novi Sad

http://orcid.org/0000-0003-1272-8499

Nina L. Finčur

University of Novi Sad Faculty of Sciences, Department of Chemistry, Biochemistry and Environmental Protection, Trg D. Obradovića 3, 21000 Novi Sad

http://orcid.org/0000-0001-6419-7576

Dragana D. Četojević-Simin

University of Novi Sad, Faculty of Medicine, Oncology Institute of Vojvodina, Dr Goldmana 4, 21204 Sremska Kamenica

http://orcid.org/0000-0002-0808-9826

Mirjana I. Čomor

University of Belgrade, Vinča Institute of Nuclear Sciences, P. O. Box 522, 11001 Belgrade

http://orcid.org/0000-0002-7222-4500

Biljana F Abramović

University of Novi Sad Faculty of Sciences, Department of Chemistry, Biochemistry and Environmental Protection, Trg D. Obradovića 3, 21000 Novi Sad

http://orcid.org/0000-0001-7009-8523

Abstract

In this paper the efficiency of photocatalytic degradation of different pesticides was investigated using bare TiO2 and TiO2 nanoparticles modified with polyaniline under simulated solar irradiation. Sulcotrione showed the highest percentage degradation and further experiments were related to this herbicide. Mineralization and cytotoxicity of the starting compound and intermediate species formed during the decomposition in double distilled water (DDW), as well as the efficiency of removal from various environmental waters were studied. The contents of the most abundant ions present in the River Danube were simulated in DDW and their influence was evaluated. It was found that cytotoxicity was in all cases below 11 % and the efficiency of photocatalytic degradation in environmental waters was decreased compared with DDW. Furthermore, addition of different scavengers revealed that the main path of degradation is through holes, while the presence of H2O2 decreased and KBrO3 increased the efficiency of photocatalytic degradation compared with the system without the mentioned electron acceptors.

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[1]

M. J. Lazarević, “Photodegradation of selected pesticides: Photocatalytic activity of bare and PANI-modified TiO2 under simulated solar irradiation”, J. Serb. Chem. Soc., vol. 84, no. 12, pp. 1455–1468, Jan. 2020.

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Vol. 84 No. 12 (2019)

Section

Environmental Chemistry

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

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