The extraction of Sr2+ with dicyclohexano-18-crown-6 in conventional organic solvent and ionic liquid diluents liquid diluents | Journal of the Serbian Chemical Society

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Published: Jul 20, 2020

DOI: https://doi.org/10.2298/JSC190417111W

Keywords:

strontium extraction crown ether diluent effect high level liquid waste

Zheng Wei

Fundamental Science on Nuclear Safety and Simulation Technology Laboratory, College of Nuclear Science and Technology, Harbin Engineering University, Harbin, Heilongjiang Province, 150001

Yang Gao

Fundamental Science on Nuclear Safety and Simulation Technology Laboratory, College of Nuclear Science and Technology, Harbin Engineering University, Harbin, Heilongjiang Province

Yu Zhou

Fundamental Science on Nuclear Safety and Simulation Technology Laboratory, College of Nuclear Science and Technology, Harbin Engineering University, Harbin, Heilongjiang Province

Caishan Jiao

Fundamental Science on Nuclear Safety and Simulation Technology Laboratory, College of Nuclear Science and Technology, Harbin Engineering University, Harbin, Heilongjiang Province

Meng Zhang

Fundamental Science on Nuclear Safety and Simulation Technology Laboratory, College of Nuclear Science and Technology, Harbin Engineering University, Harbin, Heilongjiang Province

Hongguo Hou

Fundamental Science on Nuclear Safety and Simulation Technology Laboratory, College of Nuclear Science and Technology, Harbin Engineering University, Harbin, Heilongjiang Province

Wei Liu

Nuclear Power Institute of China, Chengdu, Sichuan Province, 610005

Abstract

90Sr (t1/2 = 28.8 a), one of the most significant fission products in high-level radioactive liquid waste (HLLW), contributes to a large part of the heat load and radiation. Removal of 90Sr from the HLLW is beneficial for the final treatment of nuclear waste. In this paper, the extraction of Sr2+ was carried out using dicyclohexano-18-crown-6 (DCH18C6) in a variety of diluents including conventional organic solvents and novel ionic liquid solvents. The effect of several factors, such as nitric acid concentration, crown ether concentration and initial strontium concentration on the extraction of Sr2+ have been studied comprehensively. The higher distribution ratio and the stripping efficiency of Sr2+ were obtained with the binary diluents consisted of n-octanol and acetylene tetrachloride, which were compared with that using pure n-octanol as diluent. As for the CnmimNTf2 (n = 2, 4, 6) ionic liquid solvent systems, the distribution ratio of Sr2+ was much higher in the nitric acid medium with low concentration than in the traditional solvent systems. The results showed that DC2mimNTf2 > DC4mimNTf2 > DC6mimNTf2, which indicated that shorter carbon chain benefits the extraction of Sr2+.

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[1]

Z. Wei, “The extraction of Sr2+ with dicyclohexano-18-crown-6 in conventional organic solvent and ionic liquid diluents liquid diluents”, J. Serb. Chem. Soc., vol. 85, no. 7, pp. 909–922, Jul. 2020.

Issue

Vol. 85 No. 7 (2020)

Section

Physical Chemistry

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

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References

A. P. Paiva, P. Malik, J. Radioanal. Nucl. Chem. 261 (2004) 485 (http://dx.doi.org/10.1023/B:JRNC.0000034890.23325.b5)

P. Sinharoy, D. Banerjee, J. N. Sharma, C. P. Kaushik, J. G. Shah, J. Radioanal. Nucl. Chem. 317 (2018) 919 (http://dx.doi.org/10.1007/s10967-018-5982-2)

S. Fukushima, T. Inoue, T. Inoue, S. Ozeki, Int. J. Radiat. Oncol. Biol. Phys. 43 (1999) 597 (http://dx.doi.org/10.1016/S0360-3016(98)00431-3)

J. D. Law, R. S. Herbst, T. A. Todd, V. N. Romanovskiy, V. A. Babain, V. M. Esimantovskiy, I. V Smirnov, B. N. Zaitsev, Solvent Extr. Ion Exch. 19 (2001) 23 (http://dx.doi.org/10.1081/sei-100001371)

P. S. Dhami, C. Janardanan, P. Jagasia, S. Pahan, S. C. Tripathi, P. M. Gandhi, P. K. Wattal, J. Radioanal. Nucl. Chem. 296 (2012) 1341 (http://dx.doi.org/10.1007/s10967-012-2302-0)

V. S. Yankovskaya, I. I. Dovhyi, N. A. Bezhin, V. V. Milyutin, N. A. Nekrasova, S. V. Kapranov, V. F. Shulgin, J. Radioanal. Nucl. Chem. 318 (2018) 1085 (http://dx.doi.org/10.1007/s10967-018-6090-z)

W. W. Schulz, L. A. Bray, Sep. Sci. Technol. 22 (1987) 191 (http://dx.doi.org/10.1080/01496398708068948)

H. Y. Zhang, R. S. Wang, C. S. Lin, Y. X. Zhang, J. Radioanal. Nucl. Chem. 247 (2001) 541 (http://dx.doi.org/10.1023/A:1010630510267)

C. H. Lee, M. H. Lee, S. H. Han, Y.-K. Ha, S. Kyuseok, J. Radioanal. Nucl. Chem. 288 (2011) 319 (http://dx.doi.org/10.1007/s10967-011-0984-3)

Y. Xu, Y. Gao, Y. Zhou, C. Fan, H. Hou, M. Zhang, Solvent Extr. Ion Exch. 35 (2017) 507 (http://dx.doi.org/10.1080/07366299.2017.1373997)

C. H. Lee, H. J. Ahn, J. M. Lee, Y. K. Ha, J. Y. Kim, J. Radioanal. Nucl. Chem. 308 (2016) 809 (http://dx.doi.org/10.1007/s10967-015-4535-1)

S. J. Datta, P. Oleynikov, W. K. Moon, Y. Ma, A. Mayoral, H. Kim, C. Dejoie, M. K. Song, O. Terasaki, K. B. Yoon, Energy Environ. Sci. 12 (2019) 1857 (http://dx.doi.org/10.1039/c8ee03302a)

A. Surrao, S. W. Smith, E. Foerster, H. B. Spitz, D. G. Graczyk, J. A. Landero, F. Derek, R. M. William, B. C. Jennifer, J. Radioanal. Nucl. Chem. (2019) (http://dx.doi.org/10.1007/s10967-019-06432-w)

V. N. Romanovskiy, I. V Smirnov, V. A. Babain, T. A. Todd, R. S. Herbst, J. D. Law, K. N. Brewer, Solvent Extr. Ion Exch. 19 (2001) 1 (http://dx.doi.org/10.1081/sei-100001370)

C. J. Pedersen, J. Am. Chem. Soc. 89 (1967) 7017 (http://dx.doi.org/10.1021/ja00986a052)

E. P. Horwitz, M. L. Dietz, D. E. Fisher, Solvent Extr. Ion Exch. 8 (2007) 557 (http://dx.doi.org/10.1080/07366299008918017)

P. K. Mohapatra, P. N. Pathak, V. K. Manchanda, Talanta 45 (1997) 387 (http://dx.doi.org/10.1016/S0039-9140(97)00142-2)

D. R. Raut, P. K. Mohapatra, V. K. Manchanda, Radiochim. Acta 97 (2009) (http://dx.doi.org/10.1524/ract.2009.1660)

P. K. Mohapatra, D. S. Lakshmi, V. K. Manchanda, Desalination 198 (2006) 166 (http://dx.doi.org/10.1016/j.desal.2006.03.516)

F. Fan, F. Fan, J. Bai, W. Tian, Y. Wang, X. Wu, X. Yin, Z. Qin, J. Nucl. Radiochem. 35 (2013) 235 (http://dx.doi.org/10.7538/hhxyfshx.2013.35.04.0235)

S. H. Ha, R. N. Menchavez, Y.-M. Koo, Korean J. Chem. Eng. 27 (2010) 1360 (http://dx.doi.org/10.1007/s11814-010-0386-1)

F. Fan, Z. Qin, S. Cao, C. Tan, Q. Huang, D. Chen, J. Wang, X. Yin, C. Xu, X. Feng, Inorg. Chem. 58 (2019) 603 (http://dx.doi.org/10.1021/acs.inorgchem.8b02783)

I. Billard, A. Ouadi, C. Gaillard, Anal. Bioanal. Chem. 400 (2011) 1555 (http://dx.doi.org/10.1007/s00216-010-4478-x)

S. Dai, Y. H. Ju, C. E. Barnes, J. Chem. Soc., Dalton Trans. (1999) 1201 (http://dx.doi.org/10.1039/A809672D)

J. L. Wankowski, M. L. Dietz, Solvent Extr. Ion Exch. 34 (2016) 48 (http://dx.doi.org/10.1080/07366299.2015.1110410)

H. Luo, S. Dai, P. V Bonnesen, Anal. Chem. 76 (2004) 2773 (http://dx.doi.org/10.1021/ac035473d)

A. E. Visser, R. P. Swatloski, W. M. Reichert, S. T. Griffin, R. D. Rogers, Ind. Eng. Chem. Res. 39 (2000) 3596 (http://dx.doi.org/10.1021/ie000426m)

T. Takahashi, T. Ito, S.-Y. Kim, Energy Procedia 131 (2017) 170 (http://dx.doi.org/10.1016/j.egypro.2017.09.462)

D. R. Raut, P. K. Mohapatra, V. K. Manchanda, Sep. Sci. Technol. 45 (2010) 204 (http://dx.doi.org/10.1080/01496390903423774)

Y. Yongqing, Wanj. Heng, M. Yan, P. Xiaobing, T. Xiuhuan, X. Yan, J. Nucl. Radiochem. 29 (2007) 204 (http://dx.doi.org/10.3969/j.issn.0253-9950.2007.04.003)

H. Heitzman, B. A. Young, D. J. Rausch, P. Rickert, D. C. Stepinski, M. L. Dietz, Talanta 69 (2006) 527 (http://dx.doi.org/10.1016/j.talanta.2005.09.046)

C. Xu, X. Shen, Q. Chen, H. Gao, Sci. China, Ser. B: Chem. 52 (2009) 1858 (http://dx.doi.org/10.1007/s11426-009-0268-8)

L. Yuan, J. Peng, L. Xu, M. Zhai, J. Li, G. Wei, Dalton Trans. (2008) 6358 (http://dx.doi.org/10.1039/b811413g).