Catalytic investigation of Pd(II) complexes over Heck-Mizoroki reaction: Tailored synthesis, characterization and density functional theory

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Published: Mar 22, 2021
DOI: https://doi.org/10.2298/JSC200902075S
Keywords:
Schiff base Pd(II) derivative spectroscopic characterization molecular modeling thermogravimetric analysis cross-coupling reaction

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Satyendra Nath Shukla
Coordination Chemistry Research Lab, Department of Chemistry, Government Science College, Jabalpur (M.P.) 482001, India
https://orcid.org/0000-0002-9827-8953
Pratiksha Gaur
Coordination Chemistry Research Lab, Department of Chemistry, Government Science College, Jabalpur (M.P.) 482001, India
Sanjay Singh Bagri
Coordination Chemistry Research Lab, Department of Chemistry, Government Science College, Jabalpur (M.P.) 482001, India
Ripul Mehrotra
Instituto de Quimica Rosario Area Inorganica Facultad de Cs. Bioquimicas y Farmaceuticas Universidad Nacional de Rosario Suipacha 531 S2002LRK Rosario, Argentina
https://orcid.org/0000-0003-2620-2244
Bhaskar Chaurasia
Coordination Chemistry Research Lab, Department of Chemistry, Government Science College, Jabalpur (M.P.) 482001, India
https://orcid.org/0000-0001-5374-7157

Abstract

Tailored reaction of Schiff base ligands with palladium(II) chloride and imidazole afford three complexes of formula [Pd(II)(L)(imdz)2]Cl; where L = 2-((E)-(p-lylimino)methyl)-6-methoxyphenol (complex 1); 2-methoxy-6-((E)-(phenylimine)methyl)phenol (complex 2); and 2-((E)-(4-chloro­phenyl­imino)methyl)-6-methoxyphenol (complex 3). Compounds were characterized with elemental analysis, molar conductance, electronic spectroscopy, ESI-MS, FT-IR, TGA, 1H-NMR and 13C-NMR. Molecular structure and different quan­tum chemical parameters were calculated using the B3LYP basis set of density functional theory with the standard 6-311+G (d, 2p) level. The catalytic potential of 1-3 was examined over Heck-Mizoroki reaction and found in order of 1 > 2 > 3.

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[1]
S. N. Shukla, P. Gaur, S. S. Bagri, R. Mehrotra, and B. Chaurasia, “Catalytic investigation of Pd(II) complexes over Heck-Mizoroki reaction: Tailored synthesis, characterization and density functional theory”, J. Serb. Chem. Soc., vol. 86, no. 3, pp. 269–282, Mar. 2021.
Issue
Vol. 86 No. 3 (2021)
Section
Inorganic Chemistry
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