Ammonia removal by natural and modified clinoptilolite: Scientific paper

Aytaç Günal; Burcu Erdogan

doi:10.2298/JSC211110051G

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Published: Nov 18, 2022

Updated: 18.11.2022

DOI: https://doi.org/10.2298/JSC211110051G

Keywords:

acid activation adsorption zeolite TG/DTA XRD XRF

Aytaç Günal

Eskisehir Technical University, Graduate School of Sciences, Yunusemre Campus, 26470 Tepebasi, Eskisehir, Turkey

https://orcid.org/0000-0002-4287-6612

Burcu Erdogan

Eskisehir Technical University, Faculty of Sciece, Physiscs Department, Eskisehir, Turkey

https://orcid.org/0000-0002-2282-5375

Abstract

In this study, cation exchange and acid activation processes were applied to determine the effects of different cationic compositions of clinoptilolite on ammonia adsorption properties. Thermogravimetric (TG), differential thermal analysis (DTA), X-ray diffraction (XRD), X-ray fluorescence (XRF) and nitrogen adsorption techniques were used for the characterization of the clinoptilolite samples. As a result of ion exchange and acid activation, the amount, type and location of exchangeable cations in the structure significantly affected the thermal properties, as well as NH3 removal efficiency. Ammonia adsorption isotherms were obtained at 298 K up to 100 kPa volumetrically. In addition, NH₃ adsorption capacities of the clinoptilolite samples within this study (3.823 to 5.372 mmol g^-1) were compared with those of the other materials (1.77 to 12.2 mmol g^-1) in terms of their textural and structural differences.

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How to Cite

[1]

A. Günal and B. Erdogan, “Ammonia removal by natural and modified clinoptilolite: Scientific paper”, J. Serb. Chem. Soc., vol. 87, no. 12, pp. 1395–1407, Nov. 2022.

Issue

Vol. 87 No. 12 (2022)

Section

Physical Chemistry

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

Funding data

Anadolu Üniversitesi
Grant numbers 1602F072

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Ammonia removal by natural and modified clinoptilolite Scientific paper