Corrosion protection properties of polypyrrole coatings formed onto 316 L SS from a solution containing molybdate and salicylate Scientific paper

Article Sidebar

Graphical Abstract
PDF (2,792 kB)
Published: Nov 9, 2022
Updated: 09.11.2022
DOI: https://doi.org/10.2298/JSC220420077R
Keywords:
stainless steel conducting polymer microtubes

Main Article Content

Camila A. Ramos
Chemical Engineering Department, Institute of Electrochemical and Corrosion Engineering, National University of the South, CONICET, Bahía Blanca, Argentina
https://orcid.org/0000-0002-6723-7024
Maria Belen González
a Instituto de Ingeniería Electroquímica y Corrosión (INIEC), Departamento de Ingeniería Química, Universidad Nacional del Sur, Av. Alem 1253, (8000) Bahía Blanca, Argentina
https://orcid.org/0000-0001-6187-7912
Lorena I. Brugnoni
Department of Biology, Biochemistry and Pharmacy, Institute of Biological and Biomedical Sciences, National University of the South, CONICET, Bahía Blanca, Argentina
https://orcid.org/0000-0002-3008-1388
Silvana B. Saidman
Chemical Engineering Department, Institute of Electrochemical and Corrosion Engineering, National University of the South, CONICET, Bahía Blanca, Argentina
https://orcid.org/0000-0002-4692-3631

Abstract

The electrosynthesis of PPy films onto 316L stainless steel from nearly neutral and alkaline solutions containing molybdate and salicylate is reported. The corrosion behaviour of the coatings constituted by hollow rectan­gular microtubes was monitored in Ringer solution using open circuit potential measurements, polarization techniques and electrochemical impe­dance spectro­scopy. The polymer formed in a solution of pH 8 was the most efficient in terms of corrosion protection. The coating significantly reduced the pitting cor­rosion of the substrate. The results were interpreted taking into con­sideration the polymer electroactivity, the galvanic interaction polypyrrole/sub­strate and the nature of dopants. Silver species were effectively immobilized onto the hol­low rectangular-sectioned microtubes of PPy. The modified coat­ings demon­strated that they have a good bactericidal activity against Escher­ichia coli and they were also able to protect the substrate against corrosion in Ringer solution.

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Article Details

How to Cite
[1]
C. A. Ramos, M. B. González, L. I. Brugnoni, and S. B. Saidman, “Corrosion protection properties of polypyrrole coatings formed onto 316 L SS from a solution containing molybdate and salicylate: Scientific paper”, J. Serb. Chem. Soc., vol. 87, no. 11, pp. 1297–1311, Nov. 2022.
Issue
Vol. 87 No. 11 (2022)
Section
Electrochemistry
Creative Commons License

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Creative Commons лиценца
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

Read more....

Crossref
Scopus
Google Scholar
Europe PMC

Funding data

References

M. Z. Ibrahim, A. A. D. Sarhan, F. Y. M. Hamdi, J. Alloys Compd. 714 (2017) 636 (https://doi.org/10.1016/j.jallcom.2017.04.231)

M. J. K. Lodhi, K. M. Deen, M. C. Greenlee-Wacker, Waseem Haider, Addit. Manuf. 27 (2019) 8 (https://doi.org/10.1016/j.addma.2019.02.005)

N. S. Manam, W. S. W. Harun, D. N. A. Shri, S. A. C. Ghani, T. Kurniawan, M. H. Ismail, M. H. I. Ibrahim, J. Alloys Compd. 701 (2017) 698 (https://doi:10.1016/j.jallcom.2017.01.196)

R. K. Gupta, N. Birbilis, Corros. Sci. 92 (2015) 1 (https://doi.org/10.1016/j.corsci.2014.11.041)

C. Garcia-Cabezon, C. Garcia-Hernandez, M. L. Rodriguez-Mendez, F.Martin-Ped-rosa, J. Mat. Sci. Tech. 37 (2020) 85 (https://doi.org/10.1016/j.jmst.2019.05.071)

W. A. El-Said, M. Abdelshakour, Jin-Ha Choi, Jeong-Woo Choi, Molecules 25 (2020) 307 (https://doi:10.3390/molecules25020307)

Z. Chen, W. Yang, B. Xu, Y. Guo, Y. Chen, X. Yin, Y. Liu, Prog. Org. Coat. 122 (2018) 159 (https://doi.org/10.1016/j.porgcoat.2018.05.022)

H. M. Hung, D. K. Linh, N. T. Chinh, L. M. Duc, V. Q. Trung, Prog. Org. Coat. 131 (2019) 407 (https://doi.org/10.1016/j.porgcoat.2019.03.006)

I. L. Lehr, S.B. Saidman, Electrochim. Acta 51 (2006) 3249 (https://doi.org/10.1016/j.electacta.2005.09.017)

M. B. González, S. B. Saidman, Corr. Sci. 53 (2011) 276 (https://doi.org/10.1016/j.corsci.2010.09.021)

R. Amann, B. A. Peskar, Eur. J. Pharmacol. 447 (2002) 1 (https://doi.org/10.1016/S0014-2999(02)01828-9)

K. Cysewska, M. Gazda, P. Jasiński, Surf. Coat. Techol. 328 (2017) 248 (https://doi.org/10.1016/j.surfcoat.2017.08.055)

D. O. Flamini, M. I. Valle, M. J. Sandoval, V. L. Massheimer, S. B. Saidman, Mater. Chem. Phys. 209 (2018) 76 (https://doi.org/10.1016/j.matchemphys.2018.01.065)

A. D. Forero López, I. L. Lehr, L. I. Brugnoni, S. B. Saidman, J. Magnes. Alloys 6 (2018) 15 (https://doi.org/10.1016/j.jma.2017.12.005)

M. B. González, S. B. Saidman, Electrochem. Comm. 13 (2011) 513 (https://doi.org/10.1016/j.elecom.2011.02.037)

M. B. González, O. V. Quinzani, M. E. Vela, A. A. Rubert, G. Benítez, S. B. Saidman, Synth. Met. 162 (2012) 1133 (https://doi.org/10.1016/j.synthmet.2012.05.013)

M. B. González, S. B. Saidman, Prog. Org. Coat. 75 (2012) 178 (https://doi.org/10.1016/j.porgcoat.2012.04.015)

M. B. González, S. B. Saidman, Prog. Org. Coat. 78 (2015) 21 (http://dx.doi.org/10.1016/j.porgcoat.2014.10.012)

J. M. Brown, J. B. Mistry, J. J. Cherian, R. K. Elmallah, M. Chughtai, S. F. Harwin, Orthopedics 39 (2016) 1129 (https://doi.org/10.3928/01477447-20160819-06)

M. Wang, T. Tang, J. Orthop. Transl. 17 (2019) 42 (https://doi.org/10.1016/j.jot.2018.09.001)

M. B. González, D. O. Flamini, L. I. Brugnoni, L. M. Quinzani S. B. Saidman, J. Water Health 16 (2018) 921 (https://doi.org/10.2166/wh.2018.072)

M. B. González, L. I. Brugnoni, M. E. Vela, S. B. Saidman, Electrochim. Acta 102 (2013) 66 (https://doi.org/10.1016/j.electacta.2013.03.116)

V. Maquet, D. Martin, B. Malgrange, R. Franzen, J. Schoenen, G. Moonen, R. Jérôme, J. Biomed. Mater. Res. 52 (2000) 639 (https://doi.org/10.1002/10974636(20001215)52:4<639::AID-JBM8>3.0.CO;2-G)

P. T. Sudheesh Kumar, S. Abhilash, K. Manzoor, S.V. Nair, H. Tamura, R. Jayakumar, Carbohydr. Polym. 80 (2010) 761 (https://doi.org/10.1016/j.carbpol.2009.12.024)

Q. Pei, R. Qian, Electrochim. Acta 37 (1992) 1075 (https://doi.org/10.1016/0013-4686(92)85225-A)

S. Biallozor, A. Kupniewska, Synth. Met. 155 (2005) 443 (https://doi.org/10.1016/j.synthmet.2005.09.002)

A. A. Hermas, Corros. Sci. 50 (2008) 2498 (https://doi.org/10.1016/j.corsci.2008.06.019)

C. M. Chang, C. S. Song, H. J. Huang, J. Chin. Chem. Soc. 41 (1994) 693 (https://doi.org/10.1002/jccs.199400098)

T. Patois, B. Lakard, N. Martin, P. Fievet, Synth. Met. 160 (2010) 2180 (https://doi.org/10.1016/j.synthmet.2010.08.005)

A. El Jaouhari, A. Chennah, S. Ben Jaddi, H. Ait Ahsaine, Z. Anfar, Y. Tahiri Alaoui, Y. Naciri, A. Benlhachemi, M. Bazzaoui, Surf. Interfaces 15 (2019) 224 (https://doi.org/10.1016/j.surfin.2019.02.011)

E. Machnikova, M. Pazderova, M. Bazzaoui, N. Hackerman, Surf. Coat. Technol. 202 (2008) 1543 (https://doi.org/10.1016/j.surfcoat.2007.07.006)

D. O. Flamini, M. I. Valle, M. J. Sandoval, V. L. Massheimer, S. B. Saidman, Mater. Chem. Phys. 209 (2018) 76e85 (https://doi.org/10.1016/j.matchemphys.2018.01.065)

A. Kaynak, L. Rintoul, G. A. George, Mater. Res. Bull. 35 (2000) 813 (https://doi.org/10.1016/S0025-5408(00)00280-4)

M. K. Zadeh, M. Yeganeh, M. T. Shoushtari , A. Esmaeilkhanian, Synth. Met. 274 (2021) 116723 (https://doi.org/10.1016/j.synthmet.2021.116723)

P. P. Deshpande, N. G. Jadhav, V. J. Gelling, D. Sazou, J. Coat. Technol. Res. 11 (2014) 473 (https://doi.org/10.1016/j.surfcoat.2007.07.006)

K. A. M. Eid, H. M. E. Azzazy, Int. J. Nanomed. 7 (2012) 1543 (https://doi.org/10.2147/IJN.S26524)

S.A. Ahmad, S. S. Das, A. Khatoon, M. T. Ansari, M. Afzal, M. S. Hasnain, A. K. Nayak, Mater. Sci. Energy Technol. 3 (2020) 756 (https://doi.org/10.1016/j.mset.2020.09.002).