Exploring the properties of uranyl nicotinate: Synthesis, characterisation, and thermal analysis Scientific paper

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Published: Apr 1, 2024
Updated: 01.04.2024
DOI: https://doi.org/10.2298/JSC230817071A
Keywords:
coordination chemistry actinides thermoanalytical characterization

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Mileickson Aparecido de Assis Pires
Federal University of Grande Dourados – UFGD, Brazil
https://orcid.org/0000-0001-6897-0546
Claudio Teodoro de Carvalho
Federal University of Grande Dourados – UFGD, Brazil
Tiago André Denck Colman
Faculdade de Ciências Exatas e Tecnologia - FACET Universidade Federal da Grande Dourados - UFGD, Brazil
https://orcid.org/0000-0003-1405-4571

Abstract

This study reports the successful synthesis and characterization of a uranyl nicotinate compound, UO2(C6H4NO2)2·0.25H2O. The compound was synthesized using a metal 1:2 ligand ratio and water as the solvent. The average yield of the compound was 67 %. Thermogravimetric analysis revealed mul­tiple stages of mass loss, including dehydration, nitrogen decomposition and UO22+ reduction. Fourier-transform infrared spectroscopy confirmed the coor­din­ation of the carboxylate group in the compound. Field emission gun scan­ning electron microscope analysis showed the particles with a regular oval shape. Energy-dispersive X-ray spectroscopy provided semi-quantitative data on the elemental composition of the compound. The major elements identified were uranium, carbon, oxygen and nitrogen. These results contribute to under­standing the compound’s synthesis, thermal behaviour, molecular composition, particle morphology and elemental composition. Further research can build upon these findings to explore potential applications and develop new com­pounds with tailored properties.

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[1]
M. A. de Assis Pires, C. . Teodoro de Carvalho, and T. A. Denck Colman, “Exploring the properties of uranyl nicotinate: Synthesis, characterisation, and thermal analysis: Scientific paper”, J. Serb. Chem. Soc., vol. 89, no. 3, pp. 335–348, Apr. 2024.
Issue
Vol. 89 No. 3 (2024)
Section
Inorganic Chemistry
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References

G. Ş. Aşkın, H. Necefoğlu, G. Yılmaz Nayir, R. Çatak Çelik, T. Hökelek, Acta Crystallogr., E 71 (2015) 561 (https://doi.org/10.1107/S2056989015008270)

S. K. Verma, N. Bhojak, Int. J. Chem. Phys. Sci. 7 (2018) 67 (https://doi.org/10.30731/ijcps.7.2.2018.67-74)

M. Sertçelik, N. Delibas, H. Necefoğlu, T. Hökelek, Acta Crystallogr., E (2012) (https://doi.org/10.1107/s1600536812028814)

M. Sertçelik, B. Tercan, E. Şahin, H. Necefoğlu, T. Hökelek, Acta Crystallogr., E (2009) (https://doi.org/10.1107/s1600536809006047)

T. Hökelek, F. Yılmaz, B. Tercan, M. Sertçelik, H. Necefoğlu, Acta Crystallogr., E (2009) (https://doi.org/10.1107/s1600536809033200)

M. Sertçelik, N. Çaylak Delibaş, S. Çevik, H. Necefoğlu, T. Hökelek, Acta Crystallogr., E 68 (2012) m1196 (https://doi.org/10.1107/S1600536812035647)

G. Ş. Aşkın, H. Necefoğlu, S. Özkaya, R. Çatak Çelik, T. Hökelek, Acta Crystallogr., E 72 (2016) 888 (https://doi.org/10.1107/S2056989016008689)

G. Ş. Aşkın, H. Necefoğlu, A. M. Tonbul, N. Dilek, T. Hökelek, Acta Crystallogr., E 71 (2015) 479 (https://doi.org/10.1107/S2056989015006490)

V. A. Cocalia, M. P. Jensen, J. D. Holbrey, S. K. Spear, D. C. Stepinski, R. D. Rogers, Dalton Transactions (2005) 1966 (https://doi.org/10.1039/b502016f)

M. A. Degli-Esposti, P. J. Smolak, H. Walczak, J. Waugh, C.-P. Huang, R. F. DuBose, R. G. Goodwin, C. A. Smith, J. Exp. Med. 186 (1997) 1165 (https://doi.org/10.1084/jem.186.7.1165)

A. S. Ojo, S. Mamman, P. O. Ukoha, J. Appl. Phys. Sci. Int. (2022) 1 (https://doi.org/10.56557/japsi/2022/v14i17456)

D. Munz, Organometallics 37 (2018) 275 (https://doi.org/10.1021/acs.organomet.7b00720)

S.-S. Chen, CrystEngComm 18 (2016) 6543 (https://doi.org/10.1039/C6CE01258B)

H.-Z. Duan, C. Hu, Y.-L. Li, S.-H. Wang, Y. Xia, X. Liu, J. Wang, Y.-X. Chen, J. Am. Chem. Soc. 144 (2022) 22831 (https://doi.org/10.1021/jacs.2c09683)

K. Otake, H. Kitagawa, Small 17 (2021) 2006189 (https://doi.org/10.1002/smll.202006189)

P.-F. Yao, Y. Tao, H.-Y. Li, X.-H. Qin, D.-W. Shi, F.-P. Huang, Q. Yu, X.-X. Qin, H.-D. Bian, Cryst. Growth Des. 15 (2015) 4394 (https://doi.org/10.1021/acs.cgd.5b00724)

S. Dalai, M. Bera, A. Rana, D. S. Chowdhuri, E. Zangrando, Inorg. Chim. Acta 363 (2010) 3407 (https://doi.org/10.1016/j.ica.2010.06.043)

P. Thuéry, Inorg. Chem. Commun. 12 (2009) 800 (https://doi.org/10.1016/j.inoche.2009.06.021)

X. Kong, Y. Ren, L. Long, R. Huang, L. Zheng, Inorg. Chem. Commun. 10 (2007) 894 (https://doi.org/10.1016/j.inoche.2007.03.023)

G. T. Kent, J. Murillo, G. Wu, S. Fortier, T. W. Hayton, Inorg. Chem. 59 (2020) 8629 (https://doi.org/10.1021/acs.inorgchem.0c01224)

P. L. Arnold, D. Patel, C. Wilson, J. B. Love, Nature (2008) (https://doi.org/10.1038/nature06467)

A. Kumar, D. Lionetti, V. W. Day, J. D. Blakemore, J. Am. Chem. Soc. (2020) (https://doi.org/10.1021/jacs.9b11903)

J. A. Teixeira, W. D. G. Nunes, T. A. D. Colman, A. L. C. S. do Nascimento, F. J. Caires, F. X. Campos, D. A. Gálico, M. Ionashiro, Thermochim. Acta 624 (2016) 59 (https://doi.org/10.1016/j.tca.2015.11.023)

F. O. Farias, A. C. Jasko, T. A. D. Colman, L. A. Pinheiro, E. Schnitzler, A. C. Barana, I. M. Demiate, Braz. Arch. Biol. Technol. 57 (2014) 821 (https://doi.org/10.1590/S1516-8913201402506)

F. X. Campos, A. L. C. S. Nascimento, T. A. D. Colman, D. A. Gálico, A. C. S. Carvalho, F. J. Caires, A. B. Siqueira, M. Ionashiro, Thermochim. Acta 651 (2017) 73 (https://doi.org/10.1016/j.tca.2017.03.002)

T. A. D. Colman, D. J. C. Gomes, F. J. Caires, O. T. Filho, R. de C. da Silva, M. Ionashiro, J. Anal. Appl. Pyrolysis 111 (2015) 132 (https://doi.org/10.1016/j.jaap.2014.11.021)

A. L. C. S. do Nascimento, F. J. Caires, T. A. D. Colman, D. J. C. Gomes, G. Bannach, M. Ionashiro, Thermochim. Acta 604 (2015) 7 (https://doi.org/10.1016/j.tca.2014.12.022)

T. A. D. Colman, D. J. C. Gomes, F. J. Caires, O. T. Filho, R. de C. da Silva, M. Ionashiro, Thermochim. Acta 591 (2014) 111 (https://doi.org/10.1016/j.tca.2014.06.013)

A. S. de Souza, B. Ekawa, C. T. de Carvalho, J. A. Teixeira, M. Ionashiro, T. A. D. Colman, Thermochim. Acta 683 (2020) 178443 (https://doi.org/10.1016/j.tca.2019.178443)

K. V. Tenório, J. A. Teixeira, L. M. de Campos Pinto, F. J. Caires, O. Treu-Filho, F. A. dos Santos, T. A. Denck Colman, A. Cuin, C. T. de Carvalho, J. Rare Earths 36 (2018) 1090 (https://doi.org/10.1016/j.jre.2018.03.019)

M. D. Colman, S. R. da S. Lazzarotto, M. Lazzarotto, F. A. Hansel, T. A. D. Colman, E. Schnitzler, J. Anal. Appl. Pyrolysis 119 (2016) 157 (https://doi.org/10.1016/j.jaap.2016.03.005)

J. A. Teixeira, W. D. G. Nunes, A. L. C. S. do Nascimento, T. A. D. Colman, F. J. Caires, D. A. Gálico, M. Ionashiro, J. Anal. Appl. Pyrolysis 121 (2016) 267 (https://doi.org/10.1016/j.jaap.2016.08.0060)

C. D. Bet, C. S. de Oliveira, T. A. D. Colman, R. Z. B. Bisinella, C. Beninca, L. G. Lacerda, A. P. Ramos, E. Schnitzler, J. Therm. Anal. Calorim. 138 (2019) 2733 (https://doi.org/10.1007/s10973-019-08374-7)

C. D. Bet, C. S. de Oliveira, T. A. D. Colman, M. T. Marinho, L. G. Lacerda, A. P. Ramos, E. Schnitzler, Food Chem. 264 (2018) 435 (https://doi.org/10.1016/j.foodchem.2018.05.021)

C. A. Schneider, W. S. Rasband, K. W. Eliceiri, Nat. Methods 9 (2012) 671 (https://doi.org/10.1038/nmeth.2089)

Y. Yang, J. Liu, Y. Sun, S. Hu, Y. Gao, Z. Zhang, S. Luo, L. Rao, J. Chem. Thermodyn. 113 (2017) 350 (https://doi.org/10.1016/j.jct.2017.07.002)

J. A. Teixeira, W. D. G. Nunes, A. L. C. S. do Nascimento, T. A. D. Colman, F. J. Caires, D. A. Gálico, M. Ionashiro, J. Anal. Appl. Pyrolysis 121 (2016) 267 (https://doi.org/10.1016/j.jaap.2016.08.006)

G. Deacon, Coord. Chem. Rev. 33 (1980) 227 (https://doi.org/10.1016/S0010-8545(00)80455-5)

F. X. Campos, A. L. C. S. Nascimento, T. A. D. Colman, D. A. Gálico, O. Treu-Filho, F. J. Caires, A. B. Siqueira, M. Ionashiro, J. Therm. Anal. Calorim. 123 (2016) 91 (https://doi.org/10.1007/s10973-015-4956-7)

M. A. Abu-Dalo, N. A. F. Al-Rawashdeh, I. R. Al-Mheidat, N. S. Nassory, IOP Conf. Ser. Mater. Sci. Eng. 92 (2015) 012023 (https://doi.org/10.1088/1757-899X/92/1/012023).