Thermophysical investigation of glycol ethers in mannitol solutions at various temperatures

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Published: Aug 20, 2024
DOI: https://doi.org/10.2298/JSC230915073C
Keywords:
phenoxyethanol butoxyethanol kosmotropes chaotropic acoustic and volumetric

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Nabaparna Chakraborty
Lovely Professional University: Phagwāra, Punjab, India
https://orcid.org/0000-0003-3891-0408
Priya Thakur
Department of Physics, Lovely Professional University
Kailash Chandra Juglan
Department of Physics, Lovely Professional University
https://orcid.org/0000-0002-8753-4843
Abrar Hussain Syed
Research and Development, Saputo Dairy Australia

Abstract

Ultrasonic analysis can be very helpful to comprehend the molecular dynamics and interactions in liquid systems. Employing the Anton-Paar (DSA 5000 M) at concentrations and 0.1 MPa, sound speed as well as density of glycol ethers, i.e., phenoxyethanol (PE) and butoxyethanol (BE) in solutions of a well-known sugar alcohol (d-mannitol) were measured at 288.15-303.15 K. A variety of advanced acoustic-thermodynamic parameters, including apparent molar parameters, partial molar parameters and transfer molar properties, were estimated using the experimentally attained the velocity and density values. These derived values are used to express the interactions between solutes and their solvents. The propensity of the solute to generate or destroy structures in a solvent is also a subject of research. Analysis was done on the interactions between the molecules in the ternary mixture of d-mannitol and glycol ethers in aqueous medium.

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How to Cite
[1]
N. Chakraborty, P. Thakur, K. C. Juglan, and A. H. Syed, “Thermophysical investigation of glycol ethers in mannitol solutions at various temperatures”, J. Serb. Chem. Soc., Aug. 2024.
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Thermodynamics
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