Malachite green removal by Eryngium caeruleum ash
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Abstract
In this study, malachite green has been successfully removed from an aqueous solution with the use of Eryngium caeruleum ash as an adsorbent. The influence of effective factors on the dye removal process, like contact time, the initial concentration of dye, amount of adsorbent, temperature, and pH, has been studied. The findings revealed that optimal malachite green adsorption occurred at pH 7, 120 min of contact time, 0.01 g of adsorbent, and 100 mg L-1 of initial dye concentration. Furthermore, the adsorption results follow the Langmuir isotherm with a correlation coefficient (R2 = 0.98), (qmax = 476.19 mg g-1), and pseudo-second order kinetic (R2 = 0.97). Endothermic and spontaneous adsorption were implied by the positive ∆H°, ∆S°, and negative ∆G°. Therefore, to remove MG from aqueous solutions, Eryngium caeruleum ash can be exploited as a low-cost and environmentally friendly adsorbent.
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