Removal of pharmaceutically active substance ibuprofen from aqueous solution using TiO2/ZSM-5 zeolite hybrid photocatalysts: Scientific paper

Srna Stojanović; Marija Risitć; Danina Krajišik; Vladislav Rac; Ljiljana Damjanović-Vasilić

doi:10.2298/JSC241018098S

PDF (556 kB) Supplementary Material (385 kB)

Published: Dec 27, 2024

Updated: 27.12.2024

DOI: https://doi.org/10.2298/JSC241018098S

Keywords:

ibuprofen photocatalytic degradation titanium dioxide ZSM-5 zeolite

Srna Stojanović

University of Belgrade-Faculty of Physical Chemistry

https://orcid.org/0000-0001-9950-8303

Marija Risitć

University of Belgrade- ICTM, Department of Catalysis and Chemical Engineering

https://orcid.org/0009-0004-5262-5421

Danina Krajišik

University of Belgrade-Faculty of Pharmacy

https://orcid.org/0000-0002-5525-0109

Vladislav Rac

University of Belgrade-Faculty of Agriculture

https://orcid.org/0000-0002-2790-3950

Ljiljana Damjanović-Vasilić

Faculty of Physical Chemistry University of Belgrade Studentski trg 12-16 Belgrade, Serbia

https://orcid.org/0000-0002-7858-235X

Abstract

The removal of pharmaceutically active substance ibuprofen (IBU) from aqueous solution was studied using TiO₂/ZSM-5 zeolite hybrid photocatalysts synthesized from 20 wt. % TiO₂ P25 nanoparticles and ZSM-5 zeolites with different Si/Al ratio (11.5, 15, 25, 40 and 140). The hybrid materials were prepared by a simple and economic ultrasound assisted solid-state dispersion method and characterized by X-ray powder diffraction, Fourier transform infrared spectroscopy and ultraviolet-visible diffuse reflectance spectroscopy. Among them, the hybrid photocatalyst containing TiO₂ and ZSM-5 zeolite with a Si/Al = 40 (denoted as TZ(40)) showed the highest removal efficiency, achieving 85 % IBU removal after 80 min under UV irradiation. The optimal condition for the removal of IBU from deionized water was found to be at a natural pH 4.5. Moreover, the removal of IBU from bottled drinking water in the presence of TZ(40) hybrid material was tested. Only 32 % IBU removal was achieved because change in pH value of reaction suspension decreased efficiency of IBU removal.

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[1]

S. Stojanović, M. Risitć, D. Krajišik, V. Rac, and L. Damjanović-Vasilić, “Removal of pharmaceutically active substance ibuprofen from aqueous solution using TiO2/ZSM-5 zeolite hybrid photocatalysts: Scientific paper”, J. Serb. Chem. Soc., Dec. 2024.

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In Memoriam Issue Devoted to Prof. Dragan Veselinović

This work is licensed under a Creative Commons Attribution 4.0 International License.

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

Funding data

Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja
Grant numbers 451-03-65/2024-03/200146;451-03-66/2024-03/200026;451-03-65/2024-03/200161;451-03-66/2024-03/200161;451-03-65/2024-03/200116
Science Fund of the Republic of Serbia
Grant numbers 7309

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Removal of pharmaceutically active substance ibuprofen from aqueous solution using TiO2/ZSM-5 zeolite hybrid photocatalysts Scientific paper