Influence of hematite nanorods on the mechanical properties of epoxy resin

Main Article Content

Gordana Bogdanović
Tijana S. Kovač
Enis S. Dzunuzovic
Milena Špírková
Phillip S. Ahrenkiel
Jovan M. Nedeljković

Abstract

The mechanical properties of nanocomposites obtained by incorporation of fairly uniform hematite nanorods (α-Fe2O3 NRs) into epoxy resin were studied as a function of the content of the inorganic phase. A thorough microstructural characterization of the α-Fe2O3 NRs and the nanocomposites was performed using transmission electron microscopy (TEM) and atomic force microscopy (AFM). The TEM measurements revealed rodlike mor­pho­logy of the nanofiller with a uniform size distribution (8.5 nm×170 nm, dia­meter×length). High-magnification TEM and AFM measurements indicated agglomeration of α-Fe2O3 NRs embedded in the epoxy resin. Stress at break, strain at break, elastic modulus and tensile toughness of the nanocomposites were compared with the data obtained for pure epoxy resin. Significant inf­luence of nanofiller on the mechanical properties of epoxy resin, as well as on the glass transition temperature, could be noticed for samples with low contents of the inorganic phase (up to 1 wt. %).

Downloads

Download data is not yet available.

Metrics

Metrics Loading ...

Article Details

How to Cite
[1]
G. Bogdanović, T. S. Kovač, E. S. Dzunuzovic, M. Špírková, P. S. Ahrenkiel, and J. M. Nedeljković, “Influence of hematite nanorods on the mechanical properties of epoxy resin”, J. Serb. Chem. Soc., vol. 82, no. 4, pp. 437–447, May 2017.
Section
Polymers

References

B. Ellis, Chemistry and technology of epoxy resins, Blackie Academic & Professional, New York, 1993

B. Wetzel, P. Rosso, F. Haupert, K. Friedrich, Eng. Fract. Mech. 73 (2006) 2375

A. J. Kinloch, R. D. Mohammed, A. C. Taylor, C. Eger, S. Sprenger, D. Egan, J. Mater. Sci. 40 (2005) 5083

J. T. Han, K. Cho, Macromol. Mater. Eng. 290 (2005) 1184

G. Ragosta, M. Abbate, P. Musto, G. Scarinzi, L. Mascia, Polymer 46 (2005) 10506

J. T. Han, K. Cho, J. Mater. Sci. 41 (2006) 4239

A. J. Kinloch, A. C. Taylor, J. Mater. Sci. 41 (2006) 3271

P. Rosso, L. Ye, K. Friedrich, S. Sprenger, J. Appl. Polym. Sci. 100 (2006) 1849

H. Zhang, Z. Zhang, K. Friedrich, C. Eger, Acta Mater. 54 (2006) 1833

M. J. A. Hore, R. J. Composto, Macromolecules 47 (2014) 875

R. Scotti, L. Conzatti, M. D'Arienzo, B. Di Credico, L. Giannini, T. Hanel, P. Stagnaro, A. Susanna, L. Tadiello, F. Morazzoni, Polymer 55 (2014) 1497

A. M. Mihut, A. Sáncchez-Ferrer, J. Crassous, L. Ackerman Hirschi, R. Mezzenga, H. Dietsch, Polymer 54 (2013) 4194

E. Bugnicourt, J. Galy, J. F. Gerard, H. Barthel, Polymer 48 (2007) 1596

C. Chen, R. S. Justice, D. W. Schaefer, J. W. Baur, Polymer 49 (2008) 3805

Y. T. Bia, Z. J. Lia, W. Lianga, Polym. Adv. Technol. 25 (2014) 173

H. Gu, J. Guo, H. Wei, J. Mater. Chem., C 3 (2015) 8152

B. Wetzela, F. Hauperta, M. Q. Zhang, Compos. Sci. Technol. 63 (2003) 2055

Z. Guo, T. Pereira, O. Choi, Y. Wang, H. T. Hahn, J. Mater. Chem. 16 (2006) 2800

L. M. McGrath, R. S. Parnas, S. H. King, J. L. Schroeder, D. A. Fischer, J. L. Lenhart, Polymer 49 (2008) 999

J. M. L. Reis, D. C. Moreira, L. C. S. Nunes, L. A. Sphaier, Compos. Struct. 93 (2011) 3002

A. Chatterjee, M. S. Islam, Mat. Sci. Eng., A-Struct. 487 (2008) 574

A. Omrania, S. Afsarb, M. A. Safarpour, Mater. Chem. Phys. 122 (2010) 343

R. Medina, F. Haupert, A. K. Schlarb, J. Mater. Sci. 43 (2008) 3245

R. M. Rodgers, H. Mahfuz, V. K. Rangari, N. Chisholm, S. Jeelani, Macromol. Mater. Eng. 290 (2005) 42

J. N. Tiwari, R. N. Tiwari, K. S. Kim, Prog. Mater. Sci. 57 (2012) 724

X. Zhang, O. Alloul, Q. He, J. Zhu, M. J. Verde, Y. Li, S. Wei, Z. Guo, Polymer 54 (2013) 3594

J. Zhang, C. H. Wang, H. Niu, A. Gestos, T. Lin, X. Wang, Compos., A 55 (2013) 45

H. Gu, J. Guo, H. Wei, S. Guo, J. Liu, Y. Huang, M. A. Khan, X. Wang, D. P. Young, S. Wei, Z. Guo, Adv. Mater. 27 (2015) 6277

Q. Zhang, L. Liu, D. Jiang, X. Yan, Y. Huang, Z. Guo, J. Compos. Mater. 49 (2015) 2877

M. Abdalla, D. Dean, M. Theodore, J. Fielding, E. Nyairo, G. Price, Polymer 51 (2010) 1614

V. Djoković, J. M. Nedeljković, Macromol. Rapid Comm. 21 (2000) 994

J. Kuljanin, M. Marinović-Cincović, S. Zec, M. I. Čomor, J. M. Nedeljković, J. Mater. Sci. Lett. 22 (2003) 253

M. Marinović-Cincović, Z. V. Šaponjić, V. Djoković, S. K. Milonjić, J. M. Nedeljković, Polym. Degrad. Stabil. 91 (2006) 313

M. Marinović-Cincović, M. Č. Popović, M. M. Novaković, J. M. Nedeljković, Polym. Degrad. Stab. 92 (2007) 70

E. Džunuzović, M. Marinović-Cincović, K. Jeremić, J. Vuković, J. Nedeljković, Polym. Degrad. Stab. 93 (2008) 73

E. Džunuzović, M. Marinović-Cincović, K. Jeremić, J. Nedeljković, Polym. Degrad. Stab. 94 (2009) 701

E. Matijević, Langmuir 2 (1986) 12

V. M. Boucher, D. Cangialosi, A. Alegría, J. Colmenero, I. Pastoriza-Santos, L. M. Liz-

-Marzan, Soft Matter 7 (2011) 3607

J. G. Curro, R. R. Lagasse, Macromolecules 15 (1982) 1621

D. Dudić, M. Marinović-Cincović, J. M. Nedeljković, V. Djoković, Polymer 49 (2008) 4000

K. P. Unnikrishnan, E. T. Thachil, Des. Monomers Polym. 9 (2006) 129

T. Liu, X. Geng, Y. Nie, R. Chen, Y. Meng, X. Li, RSC Adv. 4 (2014) 30250

L. F. Low, A. Abu Bakar, J. Compos. Mater. 45 ( 2011) 2287

R. A. Pearson, A. F. Yee, Polymer 34 (1993) 3658

Z. Wang, F. Liu, W. Liang, L. Zhou, J. Reinf. Plast. Comp. 32 (2013) 1224

P. K. Ghosh, K. Kumar, N. Chaudhary, Compos., B 77 (2015) 139.

Q. H. Le, H. C. Kuan, J. B. Dai, I. Zaman, L. Luong , J. Ma, Polymer 51 (2010) 4867

J. H. Park, S. C. Jana, Polymer 44 (2003) 2091

J. Zhu, S. Wei, J. Ryu, L. Sun, Z. Luo, Z. Guo, ACS Appl. Mater. Inter. 2 (2010) 2100

B. B. Johnsen, A. J. Kinloch, R. D. Mohammed, A. C. Taylor, S. Sprenger, Polymer 48 (2007) 530

E. Bugnicourt, J. Galy, J. F. Gérard, H. Barthel, Polymer 48 (2007) 1596.

Most read articles by the same author(s)