Quantification of the binding preference of selected dyes at a solid–liquid interface in organized media

Syed Waqar Hussain Shah; Farman Ali; Iram Bibi

doi:10.2298/JSC190413078S

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Published: May 21, 2020

DOI: https://doi.org/10.2298/JSC190413078S

Keywords:

advance materials dye adsorption electronic spectral patterns anionic surfactant

Syed Waqar Hussain Shah

Department of Chemistry, Hazara University, Mansehra

Farman Ali

Department of Chemistry, Hazara University, Mansehra

Iram Bibi

Department of Chemistry, Hazara University, Mansehra

Abstract

The binding behavior of anionic dyes, acid yellow 17 and acid blue 25, at an activated carbon–liquid interface has been investigated in organized media based on aqueous sodium dodecyl sulfate using differential electronic spectroscopy. The quantification of interactions occurring in the system was realized using a simple physical model, emphasizing the displacement of bound dyes from the carbon surface. The quantities of displaced dyes were comparable; however, acid blue 25 was relatively easily desorbed compared to acid yellow 17. These differences can be attributed to differences in the dye size and hydrophobicity. The model is valid for the premicellar region of the surfactant. The results throw light on some characteristics of solid–liquid interfaces.

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[1]

S. W. H. Shah, F. Ali, and I. Bibi, “Quantification of the binding preference of selected dyes at a solid–liquid interface in organized media”, J. Serb. Chem. Soc., vol. 85, no. 5, pp. 661–670, May 2020.

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Vol. 85 No. 5 (2020)

Section

Physical Chemistry

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

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