Prediction of excess molar volumes of binary mixtures by Prigogine–Flory–Patterson (PFP) and extended real association solution (ERAS) models

Ivona Radović, Nikola Grozdanić, Bojan Djordjević, Slobodan Šerbanović, Mirjana Kijevčanin

Abstract


In this paper, Prigogine-Flory-Patterson (PFP) theoretical model and Extended Real Association Solution (ERAS) model for prediction the excess molar volumes of 17 binary sets of alcohols (methanol, ethanol, propan-1-ol, butan-1-ol, butan-2-ol, pentan-1-ol) with (benzene, chlorobenzene, acetonitrile, hexan-1-amine and n-heptane) were tested at 298.15 K and atmospheric pressure. The binary sets contained 333 experimental data points for 11 different compounds. Extended Real Association Solution (ERAS) model demonstrated better correlative characteristics for binary mixtures comparing to Prigogine-Flory-Patterson model. ERAS model is successfully applied on all binary systems except ethanol+benzene and propan-1-ol+benzene. PFP model gave less satisfactory results for all systems except butan-1-ol+hexan-1-amine for which obtained results were acceptable.

Keywords


binary mixtures, excess molar volume, prediction model, PFP, ERAS

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References


I. Prigogine, A. Bellemans, V. Mathot, The Molecular Theory of Solutions, North Holland, Amsterdam, 1957

P. J. Flory, R. A. Orwoll, A. Vrij, J. Am. Chem. Soc. 86 (1964) 3507

P. J. Flory, R. A. Orwoll, A. Vrij,J. Am. Chem. Soc. 86 (1964) 3515

P. J.Flory, J. Am. Chem. Soc. 87 (1965) 1833

A. Abe, P. J.Flory, J. Am. Chem. Soc. 87 (1965) 1838

R. A. Orwoll, P. J.Flory, J. Am. Chem. Soc. 89 (1967)6814

D. Patterson, G. Delmas, Discuss. Faraday Soc. 49 (1970) 98

A. Heintz, Ber. Bunsenges. Phys. Chem. 89 (1985) 172

I. R. Grgurić, A. Ž. Tasić, B. D. Djordjević, M. Lj. Kijevčanin, S. P. Šerbanović, J. Serb. Chem. Soc. 67 (2002) 581

M. Lj. Kijevčanin, I. M. Purić, I. R. Radović, B. D. Djordjević, S. P. Šerbanović, J. Chem. Eng. Data 52 (2007) 2067

I. R. Radović, M. Lj. Kijevčanin, S. P. Šerbanović, B. D. Djordjević, Fluid Phase Equilib. 298 (2010) 117

I. R. Radović, M. Lj. Kijevčanin, E. M. Djordjević, B. D. Djordjević, S. P. Šerbanović, Fluid Phase Equilib. 263 (2008) 205

I. R. Radović, M. Lj. Kijevčanin, A. Ž. Tasić, B. D. Djordjević, S. P. Šerbanović, J. Serb. Chem. Soc. 74 (2009) 1303

Y. Sun, L. Su, H.Wang, J. Chem. Thermodynamics 41 (2009) 1154

A. Bondi, Physical Properties of Molecular Crystals, Liquids and Glasses, John Wiley, New York, 1968

C. B. Kretschmer, R. Wiebe, J. Chem. Phys. 22 (1954) 1697

H. Renon, J.M. Prausnitz, Chem. Eng. Sci. 22 (1967) 299

H. V. Kehiaian, Bull. Acad. Pol. Sci. 16 (1968) 165

H. V. Kehiaian, A. J. Treszczanowicz, Bull. Acad. Pol. Sci. 16 (1968) 171

M. Bender, A. Heintz, Fluid Phase Equilib. 89 (1993) 197

E. N. Rezanova, K. Kammerer, R. N. Lichtenthaler, J. Chem. Thermodynamics 32 (2000) 1569

A. Heintz, P. K. Naicker, S. P. Verevkin, R. Pfestorf, Ber. Bunsen - Ges. Phys. Chem. 102 (1998) 953

R. B. Torres, A. Z. Francesconi, P. L. Volpe, Fluid Phase Equilib. 210 (2003) 287

U. Domanska, M. Gloskowska, Fluid Phase Equilib. 216 (2004) 135

B. Orge, M. Iglesias, G. Marino, M. Domınguez, M. M. Pineiro, J. Tojo, Fluid Phase Equilib. 170 (2000) 151

S. P. Ijardar, N. I. Malek, S. L. Oswal, Ind. J. Chem., A 50 (2011) 1709

S. P. Šerbanović, M. Lj. Kijevčanin, I. R. Radović, B. D. Djordjević, Fluid Phase Equilib. 239 (2006) 69

I. R. Grgurić, S. P. Šerbanović, M. Lj. Kijevčanin, A. Ž. Tasić, B. D. Djordjević, Thermochim. Acta 412 (2004) 25

J. D. Smiljanić, M. Lj. Kijevčanin, B. D. Djordjević, D. K. Grozdanić, S. P. Šerbanović, Int. J. Thermophys. 29 (2008) 586

M. Lj. Kijevčanin, I. R. Radović, S. P. Šerbanović, A. Ž. Tasić, B. D. Djordjević, Thermochim. Acta 496 (2009) 71

31. J. D. Smiljanić, M. Lj. Kijevčanin, B. D. Djordjević, D. K. Grozdanić, S. P. Šerbanović, J. Chem. Eng. Data 53 (2008) 1965

M. Lj. Kijevčanin, I. R. Radović, S. P. Šerbanović, E. M. Živković, B. D. Djordjević, J. Chem. Eng. Data 55 (2010) 1739.




DOI: http://dx.doi.org/10.2298/JSC170817103R

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