Prediction of excess molar volumes of binary mixtures by Prigogine–Flory–Patterson (PFP) and extended real association solution (ERAS) models

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Published: Dec 30, 2017
DOI: https://doi.org/10.2298/JSC170817103R
Keywords:
binary mixtures excess molar volume prediction model PFP ERAS

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Ivona Radović
Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11120 Belgrade
Nikola Grozdanić
Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11120 Belgrade
Bojan Djordjević
Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11120 Belgrade
Slobodan Šerbanović
Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11120 Belgrade
Mirjana Kijevčanin
Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11120 Belgrade

Abstract

In this paper, the Prigogine–Flory–Patterson (PFP) theoretical model and the extended real association solution (ERAS) model for the prediction of the excess molar volumes of 17 binary sets of alcohols (methanol, ethanol, pro­pan-1-ol, butan-1-ol, butan-2-ol and pentan-1-ol) with benzene, chlorobenzene, acetonitrile, hexan-1-amine and n-heptane were tested at 298.15 K and atmo­spheric pressure. The binary sets contained 333 experimental data points for 11 different compounds. The ERAS model demonstrated better correlative charac­ter­istics for binary mixtures comparing to PFP model. The ERAS model is successfully applied on all binary systems except ethanol + benzene and pro­pan-1-ol + benzene. PFP model gave less satisfactory results for all systems except butan-1-ol + hexan-1-amine, for which obtained results were acceptable.

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How to Cite
[1]
I. Radović, N. Grozdanić, B. Djordjević, S. Šerbanović, and M. Kijevčanin, “Prediction of excess molar volumes of binary mixtures by Prigogine–Flory–Patterson (PFP) and extended real association solution (ERAS) models”, J. Serb. Chem. Soc., vol. 82, no. 12, pp. 1379–1393, Dec. 2017.
Issue
Vol. 82 No. 12 (2017)
Section
Thermodynamics

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References

I. Prigogine, A. Bellemans, V. Mathot, The Molecular Theory of Solutions, North Holland, Amsterdam, 1957

P. J. Flory, R. A. Orwoll, A. Vrij, J. Am. Chem. Soc. 86 (1964) 3507

P. J. Flory, R. A. Orwoll, A. Vrij,J. Am. Chem. Soc. 86 (1964) 3515

P. J.Flory, J. Am. Chem. Soc. 87 (1965) 1833

A. Abe, P. J.Flory, J. Am. Chem. Soc. 87 (1965) 1838

R. A. Orwoll, P. J.Flory, J. Am. Chem. Soc. 89 (1967)6814

D. Patterson, G. Delmas, Discuss. Faraday Soc. 49 (1970) 98

A. Heintz, Ber. Bunsenges. Phys. Chem. 89 (1985) 172

I. R. Grgurić, A. Ž. Tasić, B. D. Djordjević, M. Lj. Kijevčanin, S. P. Šerbanović, J. Serb. Chem. Soc. 67 (2002) 581

M. Lj. Kijevčanin, I. M. Purić, I. R. Radović, B. D. Djordjević, S. P. Šerbanović, J. Chem. Eng. Data 52 (2007) 2067

I. R. Radović, M. Lj. Kijevčanin, S. P. Šerbanović, B. D. Djordjević, Fluid Phase Equilib. 298 (2010) 117

I. R. Radović, M. Lj. Kijevčanin, E. M. Djordjević, B. D. Djordjević, S. P. Šerbanović, Fluid Phase Equilib. 263 (2008) 205

I. R. Radović, M. Lj. Kijevčanin, A. Ž. Tasić, B. D. Djordjević, S. P. Šerbanović, J. Serb. Chem. Soc. 74 (2009) 1303

Y. Sun, L. Su, H.Wang, J. Chem. Thermodynamics 41 (2009) 1154

A. Bondi, Physical Properties of Molecular Crystals, Liquids and Glasses, Wiley, New York, 1968

C. B. Kretschmer, R. Wiebe, J. Chem. Phys. 22 (1954) 1697

H. Renon, J.M. Prausnitz, Chem. Eng. Sci. 22 (1967) 299

H. V. Kehiaian, Bull. Acad. Pol. Sci. 16 (1968) 165

H. V. Kehiaian, A. J. Treszczanowicz, Bull. Acad. Pol. Sci. 16 (1968) 171

M. Bender, A. Heintz, Fluid Phase Equilib. 89 (1993) 197

E. N. Rezanova, K. Kammerer, R. N. Lichtenthaler, J. Chem. Thermodynamics 32 (2000) 1569

A. Heintz, P. K. Naicker, S. P. Verevkin, R. Pfestorf, Ber. Bunsen – Ges. Phys. Chem. 102 (1998) 953

R. B. Torres, A. Z. Francesconi, P. L. Volpe, Fluid Phase Equilib. 210 (2003) 287

U. Domanska, M. Gloskowska, Fluid Phase Equilib. 216 (2004) 135

B. Orge, M. Iglesias, G. Marino, M. Domınguez, M. M. Pineiro, J. Tojo, Fluid Phase Equilib. 170 (2000) 151

S. P. Ijardar, N. I. Malek, S. L. Oswal, Ind. J. Chem., A 50 (2011) 1709

S. P. Šerbanović, M. Lj. Kijevčanin, I. R. Radović, B. D. Djordjević, Fluid Phase Equilib. 239 (2006) 69

I. R. Grgurić, S. P. Šerbanović, M. Lj. Kijevčanin, A. Ž. Tasić, B. D. Djordjević, Thermochim. Acta 412 (2004) 25

J. D. Smiljanić, M. Lj. Kijevčanin, B. D. Djordjević, D. K. Grozdanić, S. P. Šerbanović, Int. J. Thermophys. 29 (2008) 586

M. Lj. Kijevčanin, I. R. Radović, S. P. Šerbanović, A. Ž. Tasić, B. D. Djordjević, Thermochim. Acta 496 (2009) 71

31. J. D. Smiljanić, M. Lj. Kijevčanin, B. D. Djordjević, D. K. Grozdanić, S. P. Šerbanović, J. Chem. Eng. Data 53 (2008) 1965

M. Lj. Kijevčanin, I. R. Radović, S. P. Šerbanović, E. M. Živković, B. D. Djordjević, J. Chem. Eng. Data 55 (2010) 1739.