Synthesis and structural analysis of polynuclear silver(I) complexes with 4,7-phenanthroline

Ivana Stanojević, Nada D. Savić, Aurélien Crochet, Katharina M. Fromm, Miloš I. Djuran, Biljana Dj Glisic

Abstract


New polynuclear silver(I) complexes, [Ag(CF3SO3)(4,7-phen)(CH3CN)]n (1) and  [Ag(PO2F2)(4,7-phen)]n (2), were synthesized by the reaction of 4,7-phe­nanthroline (4,7-phen) and the corresponding AgX salt (X = CF3SO3-andPF6-) in 1 : 2 molar ratio, respectively, in methanol/acetone (1 : 1, v/v) at room temperature. The characterization of the complexes was established on the basis of elemental microanalysis, IR and NMR (1H and 13C) spectroscopic techniques, while their crystal structures were determined by single-crystal X-ray diffraction analysis. The results of spectroscopic and crystallographic analyses revealed that in these complexes, 4,7-phen behaves as a bridging ligand between two metal ions, while the remaining coordination sites of the Ag(I) ions are occupied by the oxygen atom of CF3SO3- and an acetonitrile nitrogen atom in 1 or by two oxygen atoms of two PO2F2- anions, formed after hydrolysis of PF6-, in 2. In the solid state, both complexes are coordination polymers in which the geometry around the Ag(I) ions is distorted tetrahedral.


Keywords


silver(I) complexes; 4,7-phenanthroline; polynuclear complexes; spec-troscopy; X-ray crystallography

Full Text:

PDF (1,234 kB)

References


A. N. Khlobystov, A. J. Blake, N. R. Champness, D. A. Lemenovskii, A. G. Majouga, N. V. Zyk, M. Schröder, Coord. Chem. Rev. 222 (2001) 155 (https://doi.org/10.1016/S0010-8545(01)00370-8)

P. Smoleński, S. W. Jaros, C. Pettinari, G. Lupidi, L. Quassinti, M. Bramucci, L. A. Vitali, D. Petrelli, A. Kochel, A. M. Kirillov, Dalton Trans. 42 (2013) 6572 (https://doi.org/10.1039/C3DT33026E)

K. Nomiya, S. Takahashi, R. Noguchi, S. Nemoto, T. Takayama, M. Oda, Inorg. Chem. 39 (2000) 3301 (https://doi.org/10.1021/ic990526o)

R. Rowan, T. Tallon, A. M. Sheahan, R. Curran, M. McCann, K. Kavanagh, M. Devereux, V. McKee, Polyhedron 25 (2006) 1771 (https://doi.org/10.1016/j.poly.2005.11.021)

S. Aslam, A. A. Isab, M. A. Alotaibi, M. Saleem, M. Monim-ul-Mehboob, S. Ahmad, I. Georgieva, N. Trendafilova, Polyhedron 115 (2016) 212 (https://doi.org/10.1016/j.poly.2016.04.047)

U. Kalinowska-Lis, A. Felczak, L. Chęcińska, K. Zawadzka, E. Patyna, K. Lisowska, J. Ochocki, Dalton Trans. 44 (2015) 8178 (https://doi.org/10.1039/C5DT00403A)

U. Kalinowska-Lis, A. Felczak, L. Chęcińska, K. Lisowska, J. Ochocki, J. Organomet. Chem. 749 (2014) 394 (https://doi.org/10.1016/j.jorganchem.2013.10.035)

C. Pettinari, F. Marchetti, G. Lupidi, L. Quassinti, M. Bramucci, D. Petrelli, L. A. Vitali, M. F. C. G. da Silva, L. M. D. R. S. Martins, P. Smoleński, A. J. Pombeiro, Inorg. Chem. 50 (2011) 11173 (https://doi.org/10.1021/ic201714c)

N. D. Savić, D. R. Milivojevic, B. Đ. Glišić, T. Ilic-Tomic, J. Veselinovic, A. Pavic, B. Vasiljevic, J. Nikodinovic-Runic, M. I. Djuran, RSC Adv. 6 (2016) 13193 (https://doi.org/10.1039/C5RA26002G)

B. Đ. Glišić, L. Senerovic, P. Comba, H. Wadepohl, A. Veselinovic, D. R. Milivojevic, M. I. Djuran, J. Nikodinovic-Runic, J. Inorg. Biochem. 155 (2016) 115 (https://doi.org/10.1016/j.jinorgbio.2015.11.026)

N. D. Savić, B. Đ. Glišić, H. Wadepohl, A. Pavic, L. Senerovic, J. Nikodinovic-Runic, M. I. Djuran, MedChemComm 7 (2016) 282 (https://doi.org/10.1039/C5MD00494B)

N. D. Savić, S. Vojnovic, B. Đ. Glišić, A. Crochet, A. Pavic, G. V. Janjić, M. Pekmezović, I. M. Opsenica, K. M. Fromm, J. Nikodinovic-Runic, M. I. Djuran, Eur. J. Med. Chem. 156 (2018) 760 (https://doi.org/10.1016/j.ejmech.2018.07.049)

T. P. Andrejević, A. M. Nikolić, B. Đ. Glišić, H. Wadepohl, S. Vojnovic, M. Zlatović, M. Petković, J. Nikodinovic-Runic, I. M. Opsenica, M. I. Djuran, Polyhedron 154 (2018) 325 (https://doi.org/10.1016/j.poly.2018.08.001)

A. Pavic, N. D. Savić, B. Đ. Glišić, A. Crochet, S. Vojnovic, A. Kurutos, D. M. Stanković, K. M. Fromm, J. Nikodinovic-Runic, M. I. Djuran, submitted

C. N. Banti, S. K. Hadjikakou, Metallomics 5 (2013) 569 (https://doi.org/10.1039/C3MT00046J)

O. Z. Yeşilel, G. Kaştaş, C. Darcan, İ. İlker, H. Paşaoğlu, O. Büyükgüngör, Inorg. Chim. Acta 363 (2010) 1849 (https://doi.org/10.1016/j.ica.2010.02.013)

D. Pucci, A. Crispini, M. Ghedini, E. I. Szerb, M. La Deda, Dalton Trans. 40 (2011) 4614 (https://doi.org/10.1039/C0DT01842B)

M. A. Fik, A. Gorczyński, M. Kubicki, Z. Hnatejko, A. Fedoruk-Wyszomirska, E. Wyszko, M. Giel-Pietraszuk, V. Patroniak, Eur. J. Med. Chem. 86 (2014) 456 (https://doi.org/10.1016/j.ejmech.2014.09.004)

O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, H. Puschmann, J. Appl. Crystallogr. 42 (2009) 339 (https://doi.org/10.1107/S0021889808042726)

G. M. Sheldrick, Acta Crystallogr. A: Found. Adv. 71 (2015) 3 (https://doi.org/10.1107/S2053273314026370)

G. M. Sheldrick, Acta Crystallogr. Sect. C: Cryst. Struct. Commun. 71 (2015) 3 (https://doi.org/10.1107/S2053229614024218)

I. J. Bruno, J. C. Cole, P. R. Edgington, M. Kessler, C. F. Macrae, P. McCabe, J. Pearson, R. Taylor, Acta Crystallogr. Sect. B: Struct. Sci. 58 (2002) 389 (https://doi.org/10.1107/S0108768102003324)

R. Fernandez‐Galan, B. R. Manzano, A. Otero, M. Lanfranchi, M. A. Pellinghelli, Inorg. Chem. 33 (1994) 2309 (https://doi.org/10.1021/ic00088a039)

P. Ovejero, M. J. Mayoral, M. Cano, J. A. Campo, J. V. Heras, E. Pinilla, M. R. Torres, J. Organomet. Chem. 692 (2007) 4093 (https://doi.org/10.1016/j.jorganchem.2007.06.015)

L. Yang, D. R. Powell, R. P. Houser, Dalton Trans. (2007) 955 (https://doi.org/10.1039/B617136B)

M. Vetrichelvan, Y.-H. Lai, K. F. Mok, Eur. J. Inorg. Chem. (2004) 2086 (https://doi.org/10.1002/ejic.200300835)

A. Melaiye, Z. Sun, K. Hindi, A. Milsted, D. Ely, D. H. Reneker, C. A. Tessier, W. J. Youngs, J. Am. Chem. Soc. 127 (2005) 2285 (https://doi.org/10.1021/ja040226s)

D. Johnston, D. F. Shriver, Inorg. Chem. 32 (1993) 1045 (https://doi.org/10.1021/ic00058a050)

G. A. van Albada, W. J. J. Smeets, A. L. Spek, J. Reedijk, Inorg. Chim. Acta 260 (1997) 151 (https://doi.org/10.1016/S0020-1693(96)05554-5)




DOI: https://doi.org/10.2298/JSC190226024S

Copyright (c) 2019 J. Serb. Chem. Soc.

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

IMPACT FACTOR 0.797 (139 of 171 journals)
5 Year Impact Factor 0.923 (134 of 171 journals)