Synthesis and structural analysis of polynuclear silver(I) complexes with 4,7-phenanthroline

Ivana Stanojević; Nada D. Savić; Aurélien Crochet; Katharina M. Fromm; Miloš I. Djuran; Biljana Dj Glišić

doi:10.2298/JSC190226024S

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Published: Jul 29, 2019

DOI: https://doi.org/10.2298/JSC190226024S

Keywords:

silver(I) complexes 4 7-phenanthroline polynuclear complexes spectroscopy X-ray crystallography

Ivana Stanojević

University of Niš, Faculty of Agriculture, Kosančićeva 4, 37000 Kruševac

Nada D. Savić

University of Kragujevac, Faculty of Science, Department of Chemistry, R. Domanovića 12, PO Box 60, 34000 Kragujevac

Aurélien Crochet

Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg

Katharina M. Fromm

Department of Chemistry, University of Fribourg, Chemin du Musée 9, CH-1700 Fribourg

Miloš I. Djuran

Serbian Academy of Sciences and Arts, Knez Mihailova 35, 11000 Belgrade

Biljana Dj Glišić

Faculty of Science, Department of Chemistry University of Kragujevac, 34000 Kragujevac

Abstract

New polynuclear silver(I) complexes, [Ag(CF₃SO₃)(4,7-
-phen)(CH₃CN)]_n (1) and [Ag(PO₂F₂)(4,7-phen)]_n (2), were synthesized by the reaction of 4,7-phenanthroline (4,7-phen) and the corresponding AgX salt (X = CF₃SO₃^-andPF₆^-) in 1:2 mole ratio, respectively, in methanol/acetone (1:1 volume ratio) at room temperature. The characterization of the complexes was established on the basis of elemental microanalysis, IR and NMR (¹H and ¹³C) spectroscopic techniques, while their crystal structures were determined by single-crystal X-ray diffraction analysis. The results of spectroscopic and crystallographic analyses revealed that in these complexes, 4,7-phen behaves as a bridging ligand between two metal ions, while the remaining coordination sites of the Ag(I) ions are occupied by the oxygen atom of CF₃SO₃^- and an acetonitrile nitrogen atom in 1 or by two oxygen atoms from two PO₂F₂^-, formed after hydrolysis of PF₆^-, in 2. In the solid state, both complexes are coordination polymers in which the geometry around the Ag(I) ions is distorted tetrahedral.

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[1]

I. Stanojević, N. D. Savić, A. Crochet, K. M. Fromm, M. I. Djuran, and B. D. Glišić, “Synthesis and structural analysis of polynuclear silver(I) complexes with 4,7-phenanthroline”, J. Serb. Chem. Soc., vol. 84, no. 7, pp. 689–699, Jul. 2019.

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Vol. 84 No. 7 (2019)

Section

Inorganic Chemistry

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

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