Synthesis, characterization and fluorescent performance studies of noveldiphenyl sulfone-functionalized water-soluble polymer

Bin Wang, Jing Ma, Xiangmei Ma

Abstract


In this communication, a novel diphenyl sulfone-functionalized water-soluble polymer was successfully synthesized through a facile hydrothermal synthesis route and then characterized by FT-IR, UV-vis, 1H-NMR and 13C-NMR spectra. Fluorescence quenching experiments revealed that the fluorescence intensities of the resulted diphenyl sulfone-functionalized polymer were linear with the concentrations of Fe3+ ions and 4-nitrophenol (4-NP) in the concentration range of (5.0~24.9)×10-8 and (5.0~50.0)×10-7 mol dm-3, with the detection limit of 2.8×10-8 and 2.2×10-7 mol dm-3, respectively. These results create opportunities for developing novel chemosensors by introducing selective fluorescent group into the polymer materials.


Keywords


Fluorescence sensing; 4-nitrophenol; Fe3+ ions; aqueous solution

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DOI: https://doi.org/10.2298/JSC200407041W

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