Supercapacitive properties of the alkali metal hydroxides-activated carbons obtained from sucrose: Scientific paper

Milica Košević; Sanja Krstić; Vladimir Panić; Branislav Nikolić

doi:10.2298/JSC220730059K

PDF (2,902 kB) Supplementary Material (2.13 MB)

Published: Jul 19, 2022

Updated: 19.07.2022

DOI: https://doi.org/10.2298/JSC220730059K

Keywords:

sucrose derived carbons alkali-treated carbon materials sugar derived carbons electrochemical capacitance distribution

Milica Košević

Institute of Chemistry, Technology and Metallurgy, National Institute of the Republic of Serbia, University of Belgrade, Njegoševa 12, 11000 Belgrade, Serbia

https://orcid.org/0000-0002-2105-4425

Sanja Krstić

University of Belgrade, Vinča Institute of Nuclear Sciences, Belgrade, Serbia

Vladimir Panić

Institute of Chemistry, Technology and Metallurgy, National Institute of the Republic of Serbia, University of Belgrade, Belgrade, Serbia; Centre of Excellence in Environmental Chemistry and Engineering – ICTM, University of Belgrade, Belgrade, Serbia and State University of Novi Pazar, Department of Natural and Mathematical Sciences, Novi Pazar, Serbia

https://orcid.org/0000-0002-8358-7956

Branislav Nikolić

Faculty of Technology and Metallurgy, University of Belgrade, Belgrade, Serbia

Abstract

The influence of different hydroxides, applied to activate carbon black, on the electrochemical properties of activated carbon was investigated. The carbon material was prepared by hydrothermal treatment of sucrose and afterwards thermally activated using KOH, NaOH and LiOH. The electrochemical properties of the obtained samples were examined by cyclic voltammetry and electrochemical impedance spectroscopy and correlated to their physicochemical properties. All samples showed characteristic capacitor-like behaviour. The highest specific capacitance was obtained for the KOH-treated sample, while the increase in capacitance follows the sequence of the growth of ionic radius of a metal from an alkali which is used for activation. It was found that the dependence on the type of hydroxide is due to differences in the radii of a metal. The alkalies of larger radii of metal generated make pores wider and consequently the structure of a porous layer become more accessible to the charge transfer of capacitive response.

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How to Cite

[1]

M. Košević, S. Krstić, V. Panić, and B. Nikolić, “Supercapacitive properties of the alkali metal hydroxides-activated carbons obtained from sucrose: Scientific paper”, J. Serb. Chem. Soc., vol. 87, no. 7-8, pp. 867–877, Jul. 2022.

Issue

Vol. 87 No. 7-8 (2022)

Section

Electrochemistry

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

Funding data

Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja
Grant numbers 451-03-68/2022-14/200026

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Supercapacitive properties of the alkali metal hydroxides-activated carbons obtained from sucrose Scientific paper