Relationship between the kinetic parameters and morphology of electrochemically deposited lead

Nebojsa D. Nikolic; Predrag M. Zivkovic; Sanja I. Stevanovic; Goran Brankovic

doi:10.2298/JSC151218028N

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Published: Jun 28, 2016

DOI: https://doi.org/10.2298/JSC151218028N

Keywords:

electrodeposition chronoamperometry diffusion Cottrell equation scanning electron microscope (SEM).

Nebojsa D. Nikolic

ICTM-Department of Electrochemistry, University of Belgrade

Predrag M. Zivkovic

Faculty of Technology and Metallurgy, University of Belgrade

Sanja I. Stevanovic

ICTM-Department of Electrochemistry, University of Belgrade

Goran Brankovic

Institute for Multidisciplinary Research, University of Belgrade

Abstract

The processes of lead electrodeposition from electrolytes of various concentrations of sodium nitrate as the supporting electrolyte have been examined by chronoamperometry and by the scanning electron microscopic (SEM) analysis of deposits obtained in the potentiostatic regime of electrolysis. The good agreement between the diffusion coefficents determined by Cottrell equation and non-linear fitting method was observed. For the first time, the transition from the mixed ohmic-diffusion to the full diffusion control was defined from the analysis of Cottrell equation. The parameters, such as the number density of active sites and the nucleation rate constant, obtained by non-linear fitting method were discussed in accordance with the fact that lead belongs to the group of metals characterized by the high values of the exchange current density. The data obtained by the chronoamperometric analysis were succesfully correlated with morphologies of electrodeposited lead obtained in the different types of electrodeposition control.

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[1]

N. D. Nikolic, P. M. Zivkovic, S. I. Stevanovic, and G. Brankovic, “Relationship between the kinetic parameters and morphology of electrochemically deposited lead”, J. Serb. Chem. Soc., vol. 81, no. 5, pp. 553–566, Jun. 2016.

Issue

Vol. 81 No. 5 (2016)

Section

Electrochemistry

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

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