Influence of electrochemical conditions on the regio- and stereoselectivity of selenocyclization of alkenyl hydantoins Short Communication

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Published: Jun 29, 2021
DOI: https://doi.org/10.2298/JSC201022023S
Keywords:
electrosynthesis constant-current electrolysis selenylation ring closure

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Biljana Šmit
Institute for Information Technologies, University of Kragujevac, Kragujevac, Serbia
http://orcid.org/0000-0001-9799-4723
Petar Stanić
Faculty of Science, University of Kragujevac, Kragujevac, Serbia
https://orcid.org/0000-0002-3655-6452
Ljubinka Joksović
Faculty of Science, University of Kragujevac, Kragujevac, Serbia
https://orcid.org/0000-0001-8781-6915
Darko Ašanin
Institute for Information Technologies, University of Kragujevac, Kragujevac, Serbia
https://orcid.org/0000-0003-1098-400X
Zoran Simić
Faculty of Science, University of Kragujevac, Kragujevac, Serbia

Abstract

5-Alkenyl hydantoins and alkenyl spirohydantoins are converted into bicyclic and tricyclic hydantoins, under indirect electrochemical conditions, generating the phenylselenyl cation in situ. The reactions proceeded in good to exelent yields. The influence of electrochemical conditions on regio- and diastereoselectivity of the selenocyclization reactions is investigated.

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How to Cite
[1]
B. Šmit, P. Stanić, L. Joksović, D. Ašanin, and Z. Simić, “Influence of electrochemical conditions on the regio- and stereoselectivity of selenocyclization of alkenyl hydantoins: Short Communication”, J. Serb. Chem. Soc., vol. 86, no. 6, pp. 585–590, Jun. 2021.
Issue
Vol. 86 No. 6 (2021)
Section
Electrochemistry
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