Synthesis and structural analysis of tetranuclear Zn(II) complex with 2,3-dihydroxybenzaldehyde-aminoguanidine: Scientific paper

Marijana Kostić; Marko Rodić; Ljiljana Vojinović-Ješić; Mirjana Radanović

doi:10.2298/JSC230808067K

PDF (1.19 MB) Supplementary Material (650 kB)

Published: Dec 25, 2023

Updated: 25.12.2023

DOI: https://doi.org/10.2298/JSC230808067K

Keywords:

Schiff base guanylhydrazones acetate coordination crystal structure

Marijana Kostić

University of Novi Sad, Faculty of Sciences, Trg Dositeja Obradovića 3, 21000, Novi Sad

https://orcid.org/0009-0005-7967-2073

Marko Rodić

University of Novi Sad, Faculty of Sciences, Trg Dositeja Obradovića 3, 21000, Novi Sad

https://orcid.org/0000-0002-4471-8001

Ljiljana Vojinović-Ješić

University of Novi Sad, Faculty of Sciences, Trg Dositeja Obradovića 3, 21000, Novi Sad

https://orcid.org/0000-0002-8618-7819

Mirjana Radanović

University of Novi Sad, Faculty of Sciences, Trg Dositeja Obradovića 3, 21000, Novi Sad

https://orcid.org/0000-0001-6675-9763

Abstract

Here we report a new Schiff base of aminoguanidine and 2,3-dihydroxybenzaldehyde (H₂L) and its physicochemical characterization, along with an investigation into its coordination affinities towards zinc. By reacting zinc acetate with the chloride salt of the ligand in the MeCN–H₂O solution, yellow single-crystals of tetranuclear, centrosymmetric complex, with the formula [Zn₂(µ-L)(µ-OAc)₂]₂∙2MeCN, were obtained. The complex was characterized by IR spectroscopy, conductometry, elemental analysis, and single-crystal X-ray diffraction analysis. Notably, both nitrogen atoms of the aminoguanidine residue coordinate to the same zinc atom, while both deprotonated phenyl oxygen atoms achieve bridging coordination. Furthermore, two acetate anions bridge adjacent zinc atoms in addition to the Schiff base anion. Meaningful insights into the hierarchy and significance of intermolecular interactions within the crystal structure were gained by estimating the energies using the CrystalExplorer model. The calculations revealed that the crystal structure can be classified as a layer type, with notably stronger interactions occurring along the [001] and [011] directions.

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[1]

M. Kostić, M. Rodić, L. Vojinović-Ješić, and M. Radanović, “Synthesis and structural analysis of tetranuclear Zn(II) complex with 2,3-dihydroxybenzaldehyde-aminoguanidine: Scientific paper”, J. Serb. Chem. Soc., vol. 88, no. 12, pp. 1253–1264, Dec. 2023.

Issue

Vol. 88 No. 12 (2023): Theme issue honoring Professor Vukadin Leovac's 80th birthday

Section

Theme issue honoring Professor Vukadin Leovac's 80th birthday

This work is licensed under a Creative Commons Attribution 4.0 International License.

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

Marijana Kostić, University of Novi Sad, Faculty of Sciences, Trg Dositeja Obradovića 3, 21000, Novi Sad

University of Novi Sad, Faculty of Sciences, Trg Dositeja Obradovića 3, 21000, Novi Sad

Marko Rodić, University of Novi Sad, Faculty of Sciences, Trg Dositeja Obradovića 3, 21000, Novi Sad

Assistant Professor
Chair of Physical Chemistry

Department of Chemistry, Biochemistry and Environmental Protection
Faculty of Sciences
University of Novi Sad

Ljiljana Vojinović-Ješić, University of Novi Sad, Faculty of Sciences, Trg Dositeja Obradovića 3, 21000, Novi Sad

University of Novi Sad, Faculty of Sciences, Trg Dositeja Obradovića 3, 21000, Novi Sad

Mirjana Radanović, University of Novi Sad, Faculty of Sciences, Trg Dositeja Obradovića 3, 21000, Novi Sad

University of Novi Sad, Faculty of Sciences, Trg Dositeja Obradovića 3, 21000, Novi Sad

Funding data

Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja
Grant numbers 451-03-47/2023-01/200125

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Synthesis and structural analysis of tetranuclear Zn(II) complex with 2,3-dihydroxybenzaldehyde-aminoguanidine Scientific paper