Structural study of Pt(II) and Pd(II) complexes with quinoline-2-carboxaldehyde thiosemicarbazone Scientific paper

Main Article Content

Predrag Ristić
https://orcid.org/0000-0002-7489-6132
Marko Rodić
https://orcid.org/0000-0002-4471-8001
Nenad Filipović
https://orcid.org/0000-0003-2982-5324
Dragana Mitić
Katarina Anđelković
https://orcid.org/0000-0001-6335-0196
Tamara Todorović
https://orcid.org/0000-0002-7740-3639

Abstract

Two square–planar complexes, [PtLCl] (1) and [PdLCl] (2), were synthesized with quinoline-2-carboxaldehyde thiosemicarbazone ligand (HL), and characterized by IR and NMR spectroscopy and single crystal X-ray dif­fract­ion analysis. In both complexes, L- is coordinated tridentately via the same donor atom set, while the fourth coordination site is occupied by a chloride ion. However, the complexes are not isostructural due to different types of non-cov­alent intermolecular interactions. These interactions were analyzed using Hirshfeld surfaces and two-dimensional fingerprint plots.

Article Details

How to Cite
[1]
P. Ristić, M. Rodić, N. Filipović, D. Mitić, K. Anđelković, and T. Todorović, “Structural study of Pt(II) and Pd(II) complexes with quinoline-2-carboxaldehyde thiosemicarbazone: Scientific paper”, J. Serb. Chem. Soc., vol. 86, no. 4, pp. 393-406, Apr. 2021.
Section
Inorganic Chemistry

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