Removal of lead and cadmium from aqueous solution using octacalcium phosphate as an adsorbent: Scientific paper

Miljana Mirković; Ana Kalijadis; Ivan Bracanović; Aleksandar Krstić; Dunja Đukić; Vladimir Dodevski

doi:10.2298/JSC230915104M

PDF (3.16 MB)

Published: Mar 4, 2024

Updated: 04.03.2024

DOI: https://doi.org/10.2298/JSC230915104M

Keywords:

calcium phosphate material adsorption water purification heavy metals

Miljana Mirković

Department of Materials „VINČA" Institute of Nuclear Sciences - National Institute of thе Republic of Serbia, University of Belgrade, Belgrade, Serbia Mike Petrovića Alasa 12-14, 11351 Vinča, Beograd, Srbija

https://orcid.org/0000-0003-2335-455X

Ana Kalijadis

Department of Materials, Vinča Institute of Nuclear Sciences - National Institute of the Republic of Serbia, University of Belgrade, Mike Petrovića Alasa 12-14, 11000 Belgrade, Serbia

https://orcid.org/0000-0002-6897-4691

Ivan Bracanović

Department of Materials, Vinča Institute of Nuclear Sciences - National Institute of the Republic of Serbia, University of Belgrade, Mike Petrovića Alasa 12-14, 11000 Belgrade, Serbia

https://orcid.org/0000-0002-8526-8633

Aleksandar Krstić

Department of Physical Chemistry, Vinča Institute of Nuclear Sciences - National Institute of the Republic of Serbia, University of Belgrade, Mike Petrovića Alasa 12-14, 11000 Belgrade, Serbia

https://orcid.org/0000-0001-7418-6723

Dunja Đukić

University of Belgrade, Faculty of Biology, Studentski Trg 16, 11000 Belgrade, Serbia

https://orcid.org/0009-0001-7863-1596

Vladimir Dodevski

Department of Materials, Vinča Institute of Nuclear Sciences - National Institute of the Republic of Serbia, University of Belgrade, Mike Petrovića Alasa 12-14, 11000 Belgrade, Serbia

https://orcid.org/0000-0003-1827-8230

Abstract

Octacalcium phosphate (OCP) is a material from the calcium phosphate group with a crystal structure similar to hydroxyapatite. The removal process of lead and cadmium in aqueous solution using octacalcium phosphate material was investigated. OCP material was synthesized by the solution precipitation method. The structural and phase properties of OCP before and after the removal process were determined by the X-ray diffraction (XRD) method. Microstructural and semi-quantitative analysis of the material was investigated by scanning electron microscopy and energy dispersive X-ray spectroscopy (SEM-EDS). Characteristic bands and functional group determination were revealed using the Fourier-transform infrared spectroscopy with attenuated total reflection (FTIR-ATR). As target pollutants, Cd(II) and Pb(II) were chosen in adsorption experiments. Results show that OCP in the first 10 min has a very fast removal rate for Pb(II); the equilibrium state was reached after 10 min with more than 98 % adsorption efficiency. Results for Cd(II), results showed the same removal rate but somewhat lower adsorption efficiency, amounted to approximately 63 %.

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[1]

M. Mirković, A. Kalijadis, I. Bracanović, A. Krstić, D. Đukić, and V. Dodevski, “Removal of lead and cadmium from aqueous solution using octacalcium phosphate as an adsorbent: Scientific paper”, J. Serb. Chem. Soc., vol. 89, no. 2, pp. 231–244, Mar. 2024.

Issue

Vol. 89 No. 2 (2024)

Section

Materials

This work is licensed under a Creative Commons Attribution 4.0 International License.

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

Funding data

Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja
Grant numbers 451-03-1/2023-03/17

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Removal of lead and cadmium from aqueous solution using octacalcium phosphate as an adsorbent Scientific paper