Electrocatalytic determination of captopril using a carbon paste electrode modified with N-(ferrocenyl-methylidene)fluorene-2-amine and graphene/ZnO nanocomposite

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Published: Mar 8, 2019
DOI: https://doi.org/10.2298/JSC180414095S
Keywords:
captopril carbon paste electrode graphene/ZnO nanocomposite N-(ferrocenylmethylidene)fluorene-2-amine

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Mohadeseh Safaei
Department of Chemistry, Faculty of Sciences, Islamic Azad University, Yazd Branch, Yazd
Hadi Beitollahi
Environment Department, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, Kerman
Masoud Reza Shishehbore
Department of Chemistry, Faculty of Sciences, Islamic Azad University, Yazd Branch, Yazd
Somayeh Tajik
NanoBioElectro¬chemistry Research Center, Bam University of Medical Sciences, Bam
Rahman hosseinzadeh
Department of Organic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar

Abstract

A carbon paste electrode (CPE) was modified with N-(ferrocenyl-methyl­id­ene)fluorene-2-amine and graphene/ZnO nanocomposite. The electro­oxidation of captopril (CAP) at the surface of the modified electrode was studied using electrochemical approaches. The electrochemical study of the modified elec­trode, as well as its efficiency for the electrocatalytic oxidation of captopril, is described. The electrode was used to study the electrocatalytic oxidation of captopril, by cyclic voltammetry (CV), chronoamperometry (CHA) and dif­fer­ential pulse voltammetry (DPV) as diagnostic techniques. It has been found that the oxidation of captopril at the surface of modified electrode occurs at a potential of about 340 mV less positive than that of an unmodified CPE. DPV of captopril at the electrochemical sensor exhibited two linear dynamic ranges (0.1–100.0 and 100.0–800.0 μM) with a detection limit (3σ) of 0.05 μM.

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How to Cite
[1]
M. Safaei, H. Beitollahi, M. R. Shishehbore, S. Tajik, and R. hosseinzadeh, “Electrocatalytic determination of captopril using a carbon paste electrode modified with N-(ferrocenyl-methylidene)fluorene-2-amine and graphene/ZnO nanocomposite”, J. Serb. Chem. Soc., vol. 84, no. 2, pp. 175–185, Mar. 2019.
Issue
Vol. 84 No. 2 (2019)
Section
Electrochemistry

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