Influence of organic/inorganic inhibitors on AISI 304 (1.4301) and AISI 314 (1.4841) steels corrosion kinetics in nitric acid solution: Scientific paper

Jelena Šćepanović; Bojana Zindović; Dragan Radonjić; Marijana Pantović Pavlović; Miroslav Pavlović

doi:10.2298/JSC240514076S

PDF (2.61 MB)

Published: Sep 10, 2024

Updated: 10.09.2024

DOI: https://doi.org/10.2298/JSC240514076S

Keywords:

austenitic stainless steel corrosion inhibitor linear polarization potentiodynamic polarization

Jelena Šćepanović

Faculty of Metallurgy and Technology, University of Montenegro, Podgorica, Montenegro

https://orcid.org/0000-0001-5841-4335

Bojana Zindović

Institute "SIGURNOST" LLC Podgorica, Montenegro

Dragan Radonjić

Faculty of Metallurgy and Technology, University of Montenegro, Podgorica, Montenegro

https://orcid.org/0000-0003-0868-4649

Marijana Pantović Pavlović

Institute of Chemistry, Technology and Metallurgy, National Institute of the Republic of Serbia, Department of Electrochemistry, University of Belgrade, Belgrade, Serbia

https://orcid.org/0000-0002-9507-3469

Miroslav Pavlović

Institute of Chemistry, Technology and Metallurgy, National Institute of the Republic of Serbia, Department of Electrochemistry, University of Belgrade, Belgrade, Serbia

https://orcid.org/0000-0003-3754-4143

Abstract

This study evaluates the effectiveness of KMnO₄, MK3 and 1-butanol inhibitors on corrosion of AISI 314 and AISI 304 stainless steels using linear and potentiodynamic polarization in 0.1 M HNO₃. The metrics like corrosion potential (E_corr), current density (j_corr) and polarization resistance (R_p) influence the inhibitor efficacy. The inhibitors improved electrochemical parameters significantly, indicating strong anti-corrosive properties. 1-Butanol had the strongest effect, enhancing corrosion potential and drastically reducing corrosion current density, demonstrating superior protection. The results indicated that without inhibitors, both steels showed higher corrosion rates and more negative potentials, reflecting their susceptibility to corrosion. The introduction of inhibitors markedly improved these parameters, particularly with 1-butanol, which significantly enhanced the polarization resistance and shifted the corrosion potential towards less negative values. The potentiodynamic results highlighted the dynamic effectiveness of inhibitors, reinforcing their role in mitigating corrosion under varied conditions. The study underscores the importance of selecting the appropriate inhibitors to enhance the durability and longevity of stainless steels in acidic environments, with 1-butanol showing the potential for industrial applications requiring high corrosion resistance. This necessitates comprehensive testing to accurately measure inhibitor capabilities in different conditions.

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[1]

J. Šćepanović, B. Zindović, D. Radonjić, M. Pantović Pavlović, and M. Pavlović, “Influence of organic/inorganic inhibitors on AISI 304 (1.4301) and AISI 314 (1.4841) steels corrosion kinetics in nitric acid solution: Scientific paper”, J. Serb. Chem. Soc., vol. 89, no. 9, pp. 1191–1210, Sep. 2024.

Issue

Vol. 89 No. 9 (2024)

Section

Electrochemistry

This work is licensed under a Creative Commons Attribution 4.0 International License.

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

Marijana Pantović Pavlović, Institute of Chemistry, Technology and Metallurgy, National Institute of the Republic of Serbia, Department of Electrochemistry, University of Belgrade, Belgrade, Serbia

Center of Excellence in Environmental Chemistry and Engineering, Institute of Chemistry, Technology and Metallurgy, Belgrade, Serbia

Miroslav Pavlović, Institute of Chemistry, Technology and Metallurgy, National Institute of the Republic of Serbia, Department of Electrochemistry, University of Belgrade, Belgrade, Serbia

Center of Excellence in Environmental Chemistry and Engineering, Institute of Chemistry, Technology and Metallurgy, Belgrade, Serbia

Funding data

Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja
Grant numbers 451-03-66/2024-03/200026

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Influence of organic/inorganic inhibitors on AISI 304 (1.4301) and AISI 314 (1.4841) steels corrosion kinetics in nitric acid solution Scientific paper