Terephthalate-bridged two-dimensional heteronuclear  Cu(II)–Mn(II) complex with terminal 2,2-dipyridylamine ligand

Lidija Radovanović; Jelena Rogan; Dejan Poleti; Marko V Rodić; Zvonko Jagličić

doi:10.2298/JSC170425086R

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Published: Dec 3, 2017

DOI: https://doi.org/10.2298/JSC170425086R

Lidija Radovanović

Innovation Center of the Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade

Jelena Rogan

Department of General and Inorganic Chemistry, Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade

Dejan Poleti

Department of General and Inorganic Chemistry, Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade

Marko V Rodić

Faculty of Sciences, University of Novi Sad, Trg Dositeja Obradovića 3, 21000 Novi Sad

Zvonko Jagličić

Faculty of Civil and Geodetic Engineering & Institute of Mathematics, Physics and Mechanics, University of Ljubljana, Jamova 2, 1000 Ljubljana

Abstract

A terephthalate-bridged heteronuclear Cu(II)–Mn(II) complex [Cu₂Mn(dipya)₂(tpht)₃]_n, I, where dipya is 2,2′-dipyridylamine and tpht is anion of 1,4-benzenedicarboxylic (terephthalic, H₂tpht) acid, has been synthesized under hydrothermal conditions. The obtained complex I was characterized by a single-crystal X-ray diffraction, FTIR spectroscopy, TG/DSC analysis and magnetic measurements. The Cu(II) and Mn(II) metal centers adopt distorted octahedral geometry and they are linked by bridging tpht ligands. Two crystallographically different tpht anions are coordinated as tridentate and hexadentate ligands forming two-dimensional layers. The layers are interconnected by hydrogen bonds and additionally stabilized by non-covalent C‑H···π interactions. The measurements of magnetic susceptibility have proven that I is an almost perfect paramagnet.

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L. Radovanović, J. Rogan, D. Poleti, M. V. Rodić, and Z. Jagličić, “Terephthalate-bridged two-dimensional heteronuclear Cu(II)–Mn(II) complex with terminal 2,2-dipyridylamine ligand”, J. Serb. Chem. Soc., vol. 82, no. 11, pp. 1247–1258, Dec. 2017.

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Vol. 82 No. 11 (2017)

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Inorganic Chemistry

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

Jelena Rogan, Department of General and Inorganic Chemistry, Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade

Department of General and Inorganic Chemistry

Dejan Poleti, Department of General and Inorganic Chemistry, Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, 11000 Belgrade

Department of General and Inorganic Chemistry

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