Synthesis, characterization and antimicrobial activity of isothiocyanato Fe(III) Girard's T hydrazone complex

Božidar Čobeljić; Andrej Pevec; Zvonko Jagličić; Milica R. Milenković; Iztok Turel; Dušanka Radanović; Marina Milenković; Katarina Anđelković

doi:10.2298/JSC180828079C

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Published: Dec 29, 2018

DOI: https://doi.org/10.2298/JSC180828079C

Keywords:

hydrazone X-ray structure magnetic properties pseudohalides

Božidar Čobeljić

Faculty of Chemistry, University of Belgrade, Studentski trg 12-16, Belgrade

Andrej Pevec

Faculty of Chemistry and Chemical Technology, University of Ljubljana, Večna pot 113, 1000 Ljubljana

Zvonko Jagličić

Institute of Mathematics, Physics and Mechanics & Faculty of Civil and Geodetic Engineering, University of Ljubljana, Jadranska 19, Ljubljana

Milica R. Milenković

Faculty of Chemistry, University of Belgrade, Studentski trg 12-16, Belgrade

Iztok Turel

Faculty of Chemistry and Chemical Technology, University of Ljubljana, Večna pot 113, 1000 Ljubljana

Dušanka Radanović

Institute of Chemistry, Technology and Metallurgy, University of Belgrade, Njegoševa 12, P.O. Box 815, 11000 Belgrade

Marina Milenković

Faculty of Pharmacy, Department of Microbiology and Immunology, University of Belgrade, Vojvode Stepe 450, 11221 Belgrade

Katarina Anđelković

Faculty of Chemistry, University of Belgrade, Studentski trg 12-16, Belgrade

Abstract

Isothiocyanato Fe(III) complex with (E)-N,N,N-trimethyl-2-oxo-2-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl)ethan-1-aminium was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray analysis. Octahedral geometry of Fe(III) complex consist of deprotonated form of hydrazone ligand coordinated through pyridine nitrogen, azomethine nitrogen and carbonyl oxygen atoms and three isothiocyanato ligands in the rest coordination places. The measured effective magnetic moment for Fe(III) complex corresponds to high spin Fe(III) ion. The hydrazone ligand and its Fe(III) complex showed lower activity against the tested microbial strains than standard antimicrobial drugs

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[1]

B. Čobeljić, “Synthesis, characterization and antimicrobial activity of isothiocyanato Fe(III) Girard’s T hydrazone complex”, J. Serb. Chem. Soc., vol. 83, no. 12, pp. 1327–1337, Dec. 2018.

Issue

Vol. 83 No. 12 (2018)

Section

Inorganic Chemistry

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution license 4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

References

L. N. Suvarapu, Y. K. Seo, S. O. Baek, V. R. Ammireddy, Eur. J. Chem. 9 (2012) 1288 (http://dx.doi.org/10.1155/2012/534617)

Lj. S. Vojinović-Ješić, S. B. Novaković, V. M. Leovac, V. I. Češljević, J. Serb. Chem. Soc. 77 (2012) 1129 (http://dx.doi.org/10.2298/JSC120704083V)

B. Čobeljić, M. Milenković, A. Pevec, I, Turel, M. Vujčić, B. Janović, N. Gligorijević, D. Sladić, S. Radulović, K. Jovanović, K. Anđelković, J. Biol. Inorg. Chem. 21 (2016) 145 (http://dx.doi.org/10.1007/s00775-015-1315-x)

M. R. Milenković, B. Čobeljić, K. Anđelković, I. Turel, Eur. J. Inorg. Chem. 2018 (2018) 838 (http://dx.doi.org/10.1002/ejic.201701387)

B. Čobeljić, A. Pevec, S. Stepanović, V. Spasojević, M. Milenković, I. Turel, M. Swart, M. Gruden-Pavlović, K. Adaila, K. Anđelković, Polyhedron 89 (2015) 271 (http://dx.¬doi.org/10.1016/j.poly.2015.01.024)

B. Čobeljić, A. Pevec, S. Stepanović, M. R. Milenković, I. Turel, M. Gruden, D. Radanović, K. Anđelković, Struct. Chem. accepted (https://doi.org/10.1007/s11224-018-1155-8)

K. Anđelković, M. R. Milenković, A. Pevec, I. Turel, I. Z. Matić, M. Vujčić, D. Sladić, D. Radanović, G. Brađan, S. Belošević, B. Čobeljić, J. Inorg. Biochem. 174 (2017) 137 (http://dx.doi.org/10.1016/j.jinorgbio.2017.06.011)

O. Kahn, Molecular Magnetism, VCH Publishing, Orsay France (1993) p. 2 (ISBN: 0471188387)

Z. Otwinowsky, W. Minor, Methods Enzymol. 276 (1997) 307 (https://doi.org/10.1016/-S0076-6879(97)76066-X)

L. J. Farrugia, J. Appl. Crystallogr. 32 (1999) 837 (http://dx.doi.org/doi:10.1107/-S0021889899006020)

A. Altomare, G. Cascarano, C. Giacovazzo, A. Guagliardi, J. Appl. Crystallogr. 26 (1993) 343 (http://dx.doi.org/https://doi.org/10.1107/S0021889892010331)

G. M. Sheldrick, Acta. Crystallogr. C71 (2015) 3 (https://doi.org/10.1107/S205322-9614024218)

K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, fourth ed., Wiley-Interscience, New York, 1986, p. 283 (https://doi.org/10.1002/¬bbpc.-198800131)

O. V. Palamarciuc, P. N. Bourosh, M. D. Revenco, J. Lipkowski, Y. A. Simonov, R. Clérac, Inorg. Chim. Acta 363 (2010) 2561 (https://doi.org/10.1016/j.ica.2010.04.027)

C. Janiak, J. Chem. Soc., Dalton Trans. (2000) 3885 (http://dx.doi.org/10.1039/B003010O)

T. Steiner, Angew. Chem. Int. Ed. 41 (2002) 48 (https://doi.org/10.1002/1521-3773(20020104)41:1<48::AID-ANIE48>3.0.CO;2-U)

L. J. Farrugia, J. Appl. Crystallogr. 45 (2012) 849 (https://doi.org/10.1107/S0021889¬812029111)

C. F.Macrae, P. R. Edgington, P. McCabe, E. Pidcock, G. P. Shields, R. Taylor, M. Towler, J. van de Streek, J. Appl. Crystallogr. 39 (2006) 453 (http://dx.doi.org/10.1107/¬S002188980600731X)

F. E. Mabbs, D. J. Machin, Magnetism and Transition Metal Complexes, Dover Publications, Inc. Mineola, New York (1973) (ISBN: 0486462846)

N. W. Ashcroft, N. D. Mermin, Solid State Physics, Saunders College Publishing, USA, (1976) (ISBN: 0030839939)

J. M. D. Coey, Magnetism and magnetic materials, Cambridge University Press, 2010 (ISBN: 978-0-521-81614-4)

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