Synthesis and characterization of palladium(II) complexes with glycine coumarin derivatives

Danijela Stojković, Alessia Bacchi, Davide Capucci, Milica R Milenković, Božidar Čobeljić, Srećko Trifunović, Katarina Anđelković, Verica V Jevtić, Nenad Vuković, Milena Vukić, Dušan Sladić

Abstract


A Pd(II) complex with methyl 2-([1-{2,4-dioxochroman-3-ylidene}­ethyl]amino)acetate was synthesized. The structures of both the ligand and its Pd(II) complex were determined by elemental analysis, and IR and NMR spectroscopy. Recrystallization of the Pd(II) complex from DMF/water solution resulted in its hydrolysis and the formation of the dimethylamine (2-[{1-(2,4-dioxochroman-3-ylidene)ethyl}amino]acetato)palladium(II) complex, the struc­ture of which was determined by elemental analysis, IR, 1H- and 13C-NMR spectroscopy and X-ray analysis.


Keywords


coumarin-derived ligands; crystal structure; mechanism of hydrolysis.

References


1. S. Emami, S. Dadashpour, Eur. J. Med. Chem. 102 (2015) 611

J. Nawrot-Modranka, E. Nawrot, J. Graczyk, Eur. J. Med. Chem. 41 (2006) 1301

V. S. Satyanarayan, P. Sreevani, A. Sivakumar, Arkivoc 2008 (2008) 221

A. G. Kidane, H. Salacinski, A. Tiwari, K. R. Bruckdorfer, A. M. Seifalian, Biomacro-molecules 5 (2004) 798

A. A. H. Kadhum, A. A. Al-Amiery, A. Y. Musa, A. B. Mohamad, Int. J. Mol. Sci. 12 (2011) 5747

G. B. Bubols, D. R. Vianna, A. Medina-Remon, G. von Poser, R. M. Lamuela-Raventos, V. L. Eifler-Lima, S. C. Garcia, Mini-Rev. Med. Chem. 13 (2013) 318

I. Kostova, I. Manolov, I. Nicolova, S. Konstantinov, M. Karaivanova, Eur. J. Med. Chem. 36 (2001) 339

A. A. Abou-Hussein, W. Linert, Spectrochim. Acta 141 (2015) 223

I. Kostova, I. Manolov, G. Momekov, Eur. J. Med. Chem. 39 (2004) 765

I. Kostova, G. Momekov, Eur. J. Med. Chem. 41 (2006) 717

I. Kostova, G. Momekov, Eur. J. Med. Chem. 43 (2008) 178

V. V. Jevtić, M. Pešić, G. P. Radić, N. Vuković, S. Sukdolak, O. Klisurić, A. Podolski-

-Renić, N. Tanić, S. R. Trifunović, J. Mol. Struct. 1040 (2013) 216

E. Budzisz, M. Małecka, I.-P. Lorenz, P. Mayer, R. A. Kwiecien, P. Paneth, U. Krajewska, M. Rozalski, Inorg. Chem. 45 (2006) 9688

E. Budzisz, B. K. Keppler, G. Giester, M. Wozniczka, A. Kufelnicki, B. Nawrot, Eur. J. Inorg. Chem. (2004) 4412

D. R. Ilić, V. V. Jevtić, G. P. Radić , K. Arsikin, B. Ristić, Lj. Harhaji-Trajković, N. Vuković, S. Sukdolak, O. Klisurić, V. Trajković, S. R. Trifunović, Eur. J. Med. Chem. 74 (2014) 502

S. Sukdolak, N. Vuković, S. Solujić, N. Manojlović, Lj. Krstić, J. Heterocycl. Chem. 41 (2004) 593

SAINT: SAX, Area Detector Integration, Siemens Analytical instruments INC., Madison, Wisconsin, USA; SADABS: Siemens Area Detector Absorption Correction Software, G. Sheldrick, 1996, University of Göttingen, Germany

M. C. Burla, R. Caliandro, B. Carrozzini, G. L. Cascarano, C. Giacovazzo, M. Mallamo, A. Mazzone, G. Polidori, Sir2011, 2011, Istituto di Ricerca per lo Sviluppo di Metodologie Cristallografiche CNR, Bari, Italy

Shelxl 97, Program for structure refinement, 1997, G. Sheldrick, University of Göttingen, Germany

O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, H. Puschmann, J. Appl. Crystallogr. 42 (2009) 339

a) F. H. Allen, O. Kennard, R. Taylor, Acc. Chem. Res. 16 (1983) 146; b) I. J. Bruno, J. C. Cole, P. R. Edgington, M. Kessler, C. F. Macrae, P. McCabe, J. Pearson, R. Taylor, Acta Crystallogr., B 58 (2002) 389

P. Y. Kuo, D. Y. Yang, J. Org. Chem. 73 (2008) 6455

M. Małecka, S. J. Grabowski, E. Budzisz, Chem. Phys. 297 (2004) 235.




DOI: https://doi.org/10.2298/JSC160915087S

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