Removal of textile dyes from water by TiO2 nanoparticles immobilized on poly(ε-caprolactone) beads and foams

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Published: Dec 29, 2018
DOI: https://doi.org/10.2298/JSC180913089M
Keywords:
poly(ε-caprolactone) TiO2 nanoparticles dye photodegradation supercritical foaming

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Darka Marković
Innovation Center of the Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, Belgrade
Stoja Milovanović
Faculty of Technology and Metallurgy University of Belgrade Belgrade, Serbia
Marija Radoičić
Institute of Nuclear Sciences "Vinča", University of Belgrade, P.O. Box 522, Belgrade
Željko Radovanović
Innovation Center of the Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, Belgrade
Irena Zizovic
Faculty of Chemistry, Wroclaw University of Science and Technology, Wybrzeze Wyspianskiego 27, 50-370, Wroclaw
Zoran Šaponjić
Institute of Nuclear Sciences "Vinča", University of Belgrade, P.O. Box 522, Belgrade
Maja Radetić
Faculty of Technology and Metallurgy University of Belgrade Belgrade, Serbia

Abstract

This study discusses the possibility of colloidal TiO2 nanoparticles (NPs) immobilization onto poly(ε-caprolactone) (PCL) beads and foams which can be utilized for removal of textile dyes from water by photodegradation. PCL foams were fabricated by environmentally friendly treatment of PCL beads in supercritical carbon-dioxide. PCL beads and foams loaded with colloidal TiO2 NPs were used as photocatalysts for the removal of textile dyes C.I. Acid Orange 7 and C.I. Basic Yellow 28 from aqueous solutions (10 mg/L) under the illumination which simulated the sunlight. Unlike the PCL beads, the PCL foams provided complete discoloration of dye solution within 24 h of illumination. The PCL foams also exhibited excellent floatability that was maintained more than four weeks. Additionally, their photocatalytic activity was preserved within three repeated photodegradation cycles indicating that floating photocatalyst provided superior photocatalytic activity compared to non-floating PCL beads.

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How to Cite
[1]
D. Marković, “Removal of textile dyes from water by TiO2 nanoparticles immobilized on poly(ε-caprolactone) beads and foams”, J. Serb. Chem. Soc., vol. 83, no. 12, pp. 1379–1389, Dec. 2018.
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Vol. 83 No. 12 (2018)
Section
Materials

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